通过残溶剂结构设计优化pvdf基电解质的输运和氧化还原性能

IF 4.2 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chemical Communications Pub Date : 2025-06-23 DOI:10.1039/d5cc01099c

Chaoyuan Ji , Shendong Tan , Bochun Liang , Ke Yang , Zihui Li , Yanfei Zhu , Yaoshu Xie , Yan-Bing He , Jia Li , Tingzheng Hou

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引用次数: 0

摘要

在聚偏氟乙烯（PVDF）基电解质中，残余溶剂对电解质的性能起着至关重要的作用。本文通过原子模型研究了各种残余溶剂对电解质性能的影响。发现氟化和分子体积的减小有利于离子快速扩散，提高循环稳定性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Optimizing the transport and redox properties of PVDF-based electrolytes through structural design of residual solvents†

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Optimizing the transport and redox properties of PVDF-based electrolytes through structural design of residual solvents†

In poly(vinylidene fluoride) (PVDF)-based electrolytes, residual solvents play a crucial role in determining the electrolyte performance. Herein, the influence of various residual solvents on electrolyte properties is investigated through atomistic modeling. It is found that fluorination and reduced molecular volume can facilitate fast ionic diffusion and enhanced cycling stability.

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来源期刊

Chemical Communications 化学-化学综合

CiteScore

8.60

自引率

4.10%

发文量

2705

审稿时长

1.4 months

期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.