{"title":"用于检测爆炸性材料的荧光金属-有机框架:当前趋势和未来展望。","authors":"Chintan Parmar, Riya Khandelwal, Mahesh Vasava","doi":"10.1007/s10895-025-04390-z","DOIUrl":null,"url":null,"abstract":"<p><p>Metal-organic frameworks (MOFs) show exceptional potential for the selective detection of hazardous analytes, including explosives, chemical warfare agents, industrial toxins, and other dangerous forensic analytes. Traditional instrumental techniques for trace explosive detection are often costly and inaccessible, creating a need for alternative solutions. MOFs offer a feasible approach through a fluorescence quenching mechanism, leveraging their tunable porosity and extensive surface area to interact specifically with nitroaromatic compounds/explosives., enabling detectable changes in fluorescence. This innovative methodology shows great potential to amplify explosive detection technologies' accessibility and efficiency. However, various challenges remain the same, such as enhancing selectivity, limit of detection, and operational stability of MOFs. This review highlights the recent advancements in MOFs-based detection strategies for nitro compounds and explosives, highlighting their advantages, challenges, limitations, and future scopes without focusing on any specific compound or detection mechanism. By addressing these limitations, MOFs can further strengthen their role in enhancing rapid and reliable detection methods for hazardous analytes.</p>","PeriodicalId":15800,"journal":{"name":"Journal of Fluorescence","volume":" ","pages":""},"PeriodicalIF":2.6000,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fluorescent Metal-Organic Frameworks for the Detection of Explosive Materials: Current Trends and Future Prospects.\",\"authors\":\"Chintan Parmar, Riya Khandelwal, Mahesh Vasava\",\"doi\":\"10.1007/s10895-025-04390-z\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Metal-organic frameworks (MOFs) show exceptional potential for the selective detection of hazardous analytes, including explosives, chemical warfare agents, industrial toxins, and other dangerous forensic analytes. Traditional instrumental techniques for trace explosive detection are often costly and inaccessible, creating a need for alternative solutions. MOFs offer a feasible approach through a fluorescence quenching mechanism, leveraging their tunable porosity and extensive surface area to interact specifically with nitroaromatic compounds/explosives., enabling detectable changes in fluorescence. This innovative methodology shows great potential to amplify explosive detection technologies' accessibility and efficiency. However, various challenges remain the same, such as enhancing selectivity, limit of detection, and operational stability of MOFs. This review highlights the recent advancements in MOFs-based detection strategies for nitro compounds and explosives, highlighting their advantages, challenges, limitations, and future scopes without focusing on any specific compound or detection mechanism. By addressing these limitations, MOFs can further strengthen their role in enhancing rapid and reliable detection methods for hazardous analytes.</p>\",\"PeriodicalId\":15800,\"journal\":{\"name\":\"Journal of Fluorescence\",\"volume\":\" \",\"pages\":\"\"},\"PeriodicalIF\":2.6000,\"publicationDate\":\"2025-06-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fluorescence\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1007/s10895-025-04390-z\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"BIOCHEMICAL RESEARCH METHODS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fluorescence","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1007/s10895-025-04390-z","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"BIOCHEMICAL RESEARCH METHODS","Score":null,"Total":0}
Fluorescent Metal-Organic Frameworks for the Detection of Explosive Materials: Current Trends and Future Prospects.
Metal-organic frameworks (MOFs) show exceptional potential for the selective detection of hazardous analytes, including explosives, chemical warfare agents, industrial toxins, and other dangerous forensic analytes. Traditional instrumental techniques for trace explosive detection are often costly and inaccessible, creating a need for alternative solutions. MOFs offer a feasible approach through a fluorescence quenching mechanism, leveraging their tunable porosity and extensive surface area to interact specifically with nitroaromatic compounds/explosives., enabling detectable changes in fluorescence. This innovative methodology shows great potential to amplify explosive detection technologies' accessibility and efficiency. However, various challenges remain the same, such as enhancing selectivity, limit of detection, and operational stability of MOFs. This review highlights the recent advancements in MOFs-based detection strategies for nitro compounds and explosives, highlighting their advantages, challenges, limitations, and future scopes without focusing on any specific compound or detection mechanism. By addressing these limitations, MOFs can further strengthen their role in enhancing rapid and reliable detection methods for hazardous analytes.
期刊介绍:
Journal of Fluorescence is an international forum for the publication of peer-reviewed original articles that advance the practice of this established spectroscopic technique. Topics covered include advances in theory/and or data analysis, studies of the photophysics of aromatic molecules, solvent, and environmental effects, development of stationary or time-resolved measurements, advances in fluorescence microscopy, imaging, photobleaching/recovery measurements, and/or phosphorescence for studies of cell biology, chemical biology and the advanced uses of fluorescence in flow cytometry/analysis, immunology, high throughput screening/drug discovery, DNA sequencing/arrays, genomics and proteomics. Typical applications might include studies of macromolecular dynamics and conformation, intracellular chemistry, and gene expression. The journal also publishes papers that describe the synthesis and characterization of new fluorophores, particularly those displaying unique sensitivities and/or optical properties. In addition to original articles, the Journal also publishes reviews, rapid communications, short communications, letters to the editor, topical news articles, and technical and design notes.