{"title":"K2CO3和三聚氰胺对提高枣石基超级电容器性能的协同效应。","authors":"Atif Saeed Alzahrani","doi":"10.1002/open.202500271","DOIUrl":null,"url":null,"abstract":"<p><p>Biomass-derived carbon materials play a crucial role in advancing electrochemical energy storage technologies toward a cleaner and more sustainable future. This study investigates the potential of date stone biomass as a sustainable precursor for fabricating high-performance supercapacitor electrodes. A two-stage pyrolysis process is utilized, incorporating K<sub>2</sub>CO<sub>3</sub> as an activating agent and melamine as a nitrogen dopant. The synergistic interaction of these additives results in an activated carbon material with a significantly improved surface area, pore volume, and nitrogen content. The electrochemical analysis reveals a high specific capacitance of 209.36 F g<sup>-1</sup> at 0.5 A g<sup>-1</sup>, excellent cycling stability over 5000 cycles at 10 A g<sup>-1</sup>, and high energy and power densities (24.47 Wh kg<sup>-1</sup> at 2500 W kg<sup>-1</sup>). This study demonstrates the feasibility of utilizing date stone biomass as a renewable resource for advanced carbon-based materials in energy storage applications, contributing to a more sustainable future.</p>","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500271"},"PeriodicalIF":2.5000,"publicationDate":"2025-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synergistic Effects of K<sub>2</sub>CO<sub>3</sub> and Melamine on Enhancing the Performance of Date Stone-Derived Supercapacitors.\",\"authors\":\"Atif Saeed Alzahrani\",\"doi\":\"10.1002/open.202500271\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Biomass-derived carbon materials play a crucial role in advancing electrochemical energy storage technologies toward a cleaner and more sustainable future. This study investigates the potential of date stone biomass as a sustainable precursor for fabricating high-performance supercapacitor electrodes. A two-stage pyrolysis process is utilized, incorporating K<sub>2</sub>CO<sub>3</sub> as an activating agent and melamine as a nitrogen dopant. The synergistic interaction of these additives results in an activated carbon material with a significantly improved surface area, pore volume, and nitrogen content. The electrochemical analysis reveals a high specific capacitance of 209.36 F g<sup>-1</sup> at 0.5 A g<sup>-1</sup>, excellent cycling stability over 5000 cycles at 10 A g<sup>-1</sup>, and high energy and power densities (24.47 Wh kg<sup>-1</sup> at 2500 W kg<sup>-1</sup>). This study demonstrates the feasibility of utilizing date stone biomass as a renewable resource for advanced carbon-based materials in energy storage applications, contributing to a more sustainable future.</p>\",\"PeriodicalId\":9831,\"journal\":{\"name\":\"ChemistryOpen\",\"volume\":\" \",\"pages\":\"e2500271\"},\"PeriodicalIF\":2.5000,\"publicationDate\":\"2025-06-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ChemistryOpen\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1002/open.202500271\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ChemistryOpen","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1002/open.202500271","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
生物质衍生的碳材料在推动电化学储能技术朝着更清洁、更可持续的未来发展方面发挥着至关重要的作用。本研究探讨了枣石生物质作为制造高性能超级电容器电极的可持续前体的潜力。采用K2CO3为活化剂,三聚氰胺为氮掺杂剂的两段热解工艺。这些添加剂的协同作用导致活性炭材料具有显着改善的表面积,孔隙体积和氮含量。电化学分析表明,该材料在0.5 a g-1下具有209.36 F -1的高比电容,在10 a g-1下具有超过5000次循环的优异循环稳定性,并且具有较高的能量和功率密度(在2500 W kg-1下为24.47 Wh kg-1)。该研究证明了利用枣石生物质作为先进碳基材料储能应用的可再生资源的可行性,有助于实现更可持续的未来。
Synergistic Effects of K2CO3 and Melamine on Enhancing the Performance of Date Stone-Derived Supercapacitors.
Biomass-derived carbon materials play a crucial role in advancing electrochemical energy storage technologies toward a cleaner and more sustainable future. This study investigates the potential of date stone biomass as a sustainable precursor for fabricating high-performance supercapacitor electrodes. A two-stage pyrolysis process is utilized, incorporating K2CO3 as an activating agent and melamine as a nitrogen dopant. The synergistic interaction of these additives results in an activated carbon material with a significantly improved surface area, pore volume, and nitrogen content. The electrochemical analysis reveals a high specific capacitance of 209.36 F g-1 at 0.5 A g-1, excellent cycling stability over 5000 cycles at 10 A g-1, and high energy and power densities (24.47 Wh kg-1 at 2500 W kg-1). This study demonstrates the feasibility of utilizing date stone biomass as a renewable resource for advanced carbon-based materials in energy storage applications, contributing to a more sustainable future.
期刊介绍:
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