利用电子鼻顶空分析检测低碳钢和不锈钢的锈蚀

IF 4.3 2区综合性期刊 Q1 ENGINEERING, ELECTRICAL & ELECTRONIC

IEEE Sensors Journal Pub Date : 2025-04-23 DOI:10.1109/JSEN.2025.3562033

I. Carotti;D. R. Billson;D. A. Hutchins;P. Liddicott;J. A. Covington

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引用次数: 0

摘要

腐蚀是各行各业面临的重大挑战，需要持续监测以防止灾难性故障。本研究探索了一种非侵入式腐蚀检测的替代方法，通过识别由氧化还原反应或锈迹与其环境之间的催化相互作用产生的副产品，从而导致气态化合物的排放。利用电子鼻（eNoses），特别是AlphaMOS FOX4000和定制的Warwick OLFaction (WOLF)，我们分析了生锈样品的化学顶空，并与对照样品进行了比较。结果表明，在规定的腐蚀时间间隔（从1小时到2个月）内，生锈样品环境中的化学成分（包括低碳钢、不锈钢、空气和腐蚀促进剂空白）发生了明显的变化。主成分分析（PCA）揭示了不同时间点腐蚀样品之间的独特簇，说明了生锈和未生锈样品之间的显着差异，以及腐蚀样品之间基于腐蚀持续时间的变化。我们的研究结果证明了enses在无创腐蚀检测方面的潜力，可以应用于维护关键基础设施的结构完整性和提高安全性。

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Detection of Rust Corrosion in Mild Steel and Stainless Steel Through Headspace Analysis by Electronic Noses

Corrosion poses a significant challenge across various industries, necessitating continuous monitoring to prevent catastrophic failures. This study explores an alternative noninvasive approach to corrosion detection by identifying by-products resulting from redox reactions or catalytic interactions between rust and its environment, leading to the emission of gaseous compounds. Utilizing electronic noses (eNoses), specifically the AlphaMOS FOX4000 and the custom-built Warwick OLFaction (WOLF), we analyzed the chemical headspace of rusted samples in comparison with control samples. The results indicated discernible variations in the chemical compounds within the rusted sample environments, including mild steel, stainless steel, air, and corrosion accelerant blanks, over specified corrosion time intervals ranging from 1 h to two months. Principal component analysis (PCA) unveiled distinctive clusters among corroded samples at different time points, illustrating notable disparities between rusted and nonrusted samples, as well as variations among the corroded samples based on the duration of corrosion. Our findings demonstrate the potential of eNoses for noninvasive corrosion detection, with applications in maintaining structural integrity and enhancing safety in critical infrastructure.

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来源期刊

IEEE Sensors Journal 工程技术-工程：电子与电气

CiteScore

7.70

自引率

14.00%

发文量

2058

审稿时长

5.2 months

期刊介绍： The fields of interest of the IEEE Sensors Journal are the theory, design , fabrication, manufacturing and applications of devices for sensing and transducing physical, chemical and biological phenomena, with emphasis on the electronics and physics aspect of sensors and integrated sensors-actuators. IEEE Sensors Journal deals with the following: -Sensor Phenomenology, Modelling, and Evaluation -Sensor Materials, Processing, and Fabrication -Chemical and Gas Sensors -Microfluidics and Biosensors -Optical Sensors -Physical Sensors: Temperature, Mechanical, Magnetic, and others -Acoustic and Ultrasonic Sensors -Sensor Packaging -Sensor Networks -Sensor Applications -Sensor Systems: Signals, Processing, and Interfaces -Actuators and Sensor Power Systems -Sensor Signal Processing for high precision and stability (amplification, filtering, linearization, modulation/demodulation) and under harsh conditions (EMC, radiation, humidity, temperature); energy consumption/harvesting -Sensor Data Processing (soft computing with sensor data, e.g., pattern recognition, machine learning, evolutionary computation; sensor data fusion, processing of wave e.g., electromagnetic and acoustic; and non-wave, e.g., chemical, gravity, particle, thermal, radiative and non-radiative sensor data, detection, estimation and classification based on sensor data) -Sensors in Industrial Practice