苯甲酰胺不同晶型对有机-无机杂化金属卤化物中Mn2+发光性能影响的研究

IF 3.1 4区物理与天体物理 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY

Current Applied Physics Pub Date : 2025-06-13 DOI:10.1016/j.cap.2025.06.007

Mengyu Guan, Ranran Bu, Haizhen Song, Changyuan Xu, Yichao Wang, Yan Zhang, Hongming Yin

{"title":"苯甲酰胺不同晶型对有机-无机杂化金属卤化物中Mn2+发光性能影响的研究","authors":"Mengyu Guan, Ranran Bu, Haizhen Song, Changyuan Xu, Yichao Wang, Yan Zhang, Hongming Yin","doi":"10.1016/j.cap.2025.06.007","DOIUrl":null,"url":null,"abstract":"<div><div>Mn<sup>2+</sup>-based organic-inorganic hybrid metal halides were synthesized via evaporation crystallization using benzamide (BZM) and nicotinamide (NCM) as organic ligands. The DSC curve shows that the Mn<sup>2+</sup>-based organic-inorganic hybrid metal halides contain two crystal forms of BZM. Steady-state photoluminescence (PL) spectra reveal that the PL emission of Mn<sup>2+</sup> shifts from red to green as the crystal form of BZM changes. Density functional theory (DFT) calculation suggests that there is a certain rule between the transformation of BZM crystal form and the change of Mn<sup>2+</sup> luminescence characteristics.</div></div>","PeriodicalId":11037,"journal":{"name":"Current Applied Physics","volume":"77 ","pages":"Pages 116-122"},"PeriodicalIF":3.1000,"publicationDate":"2025-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study on the effect of different crystal forms of benzamide on the luminescence properties of Mn2+ in organic-inorganic hybrid metal halides\",\"authors\":\"Mengyu Guan, Ranran Bu, Haizhen Song, Changyuan Xu, Yichao Wang, Yan Zhang, Hongming Yin\",\"doi\":\"10.1016/j.cap.2025.06.007\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Mn<sup>2+</sup>-based organic-inorganic hybrid metal halides were synthesized via evaporation crystallization using benzamide (BZM) and nicotinamide (NCM) as organic ligands. The DSC curve shows that the Mn<sup>2+</sup>-based organic-inorganic hybrid metal halides contain two crystal forms of BZM. Steady-state photoluminescence (PL) spectra reveal that the PL emission of Mn<sup>2+</sup> shifts from red to green as the crystal form of BZM changes. Density functional theory (DFT) calculation suggests that there is a certain rule between the transformation of BZM crystal form and the change of Mn<sup>2+</sup> luminescence characteristics.</div></div>\",\"PeriodicalId\":11037,\"journal\":{\"name\":\"Current Applied Physics\",\"volume\":\"77 \",\"pages\":\"Pages 116-122\"},\"PeriodicalIF\":3.1000,\"publicationDate\":\"2025-06-13\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Current Applied Physics\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1567173925001270\",\"RegionNum\":4,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Current Applied Physics","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1567173925001270","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

以苯甲酰胺（BZM）和烟酰胺（NCM）为有机配体，通过蒸发结晶法制备了Mn2+基有机-无机杂化金属卤化物。DSC曲线表明，Mn2+基有机-无机杂化金属卤化物含有两种BZM晶型。稳态光致发光（PL）光谱显示，随着BZM晶体形态的变化，Mn2+的PL发射从红色变为绿色。密度泛函理论（DFT）计算表明，BZM晶型的转变与Mn2+发光特性的变化之间存在一定的规律。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Study on the effect of different crystal forms of benzamide on the luminescence properties of Mn2+ in organic-inorganic hybrid metal halides

查看原文本刊更多论文

Study on the effect of different crystal forms of benzamide on the luminescence properties of Mn2+ in organic-inorganic hybrid metal halides

Mn²⁺-based organic-inorganic hybrid metal halides were synthesized via evaporation crystallization using benzamide (BZM) and nicotinamide (NCM) as organic ligands. The DSC curve shows that the Mn²⁺-based organic-inorganic hybrid metal halides contain two crystal forms of BZM. Steady-state photoluminescence (PL) spectra reveal that the PL emission of Mn²⁺ shifts from red to green as the crystal form of BZM changes. Density functional theory (DFT) calculation suggests that there is a certain rule between the transformation of BZM crystal form and the change of Mn²⁺ luminescence characteristics.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Current Applied Physics 物理-材料科学：综合

CiteScore

4.80

自引率

0.00%

发文量

213

审稿时长

33 days

期刊介绍： Current Applied Physics (Curr. Appl. Phys.) is a monthly published international journal covering all the fields of applied science investigating the physics of the advanced materials for future applications. Other areas covered: Experimental and theoretical aspects of advanced materials and devices dealing with synthesis or structural chemistry, physical and electronic properties, photonics, engineering applications, and uniquely pertinent measurement or analytical techniques. Current Applied Physics, published since 2001, covers physics, chemistry and materials science, including bio-materials, with their engineering aspects. It is a truly interdisciplinary journal opening a forum for scientists of all related fields, a unique point of the journal discriminating it from other worldwide and/or Pacific Rim applied physics journals. Regular research papers, letters and review articles with contents meeting the scope of the journal will be considered for publication after peer review. The Journal is owned by the Korean Physical Society.