3-对称手性笼形磷酸盐的合成及其在不对称碘化反应中的应用[j]。化学6/2025)

IF 2.8 4区化学 Q1 CHEMISTRY, ORGANIC

Asian Journal of Organic Chemistry Pub Date : 2025-06-16 DOI:10.1002/ajoc.202580602

Xiao Liu, Dr. Akihito Konishi, Prof. Dr. Makoto Yasuda

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引用次数: 0

摘要

c3对称的笼形磷酸盐创造了一个螺旋手性环境，其功能就像一个单向的漩涡。当线性起始材料进入这种手性环境时，它就转化为精确控制的立体化学产物。这种转变代表了手性漩涡是如何使龙卷成线圈的！封面图片描绘了龙的转变，这是由我们的涡流状催化剂催化的。更多细节可以在编号e202500299的文章中找到，作者是小刘、小西明仁和安田诚。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Cover Feature: C3-Symmetric Chiral Cage-Shaped Phosphates: Synthesis and Application as Organocatalysts in Asymmetric Iodolactonizations (Asian J. Org. Chem. 6/2025)

The C₃-symmetric, cage-shaped phosphate creates a helical chiral environment that functions like a vortex with a single direction. When a linear starting material enters this chiral environment, it is transformed into a precisely controlled stereochemical product. This transformation represents how the chiral vortex causes a dragon to curl up into a coil! The cover image depicts the dragon's transformation, which is catalyzed by our vortex-shaped catalyst. More details can be found in article number e202500299 by Xiao Liu, Akihito Konishi, and Makoto Yasuda.

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来源期刊

Asian Journal of Organic Chemistry CHEMISTRY, ORGANIC-

CiteScore

4.70

自引率

3.70%

发文量

372

期刊介绍： Organic chemistry is the fundamental science that stands at the heart of chemistry, biology, and materials science. Research in these areas is vigorous and truly international, with three major regions making almost equal contributions: America, Europe and Asia. Asia now has its own top international organic chemistry journal—the Asian Journal of Organic Chemistry (AsianJOC) The AsianJOC is designed to be a top-ranked international research journal and publishes primary research as well as critical secondary information from authors across the world. The journal covers organic chemistry in its entirety. Authors and readers come from academia, the chemical industry, and government laboratories.