内页图片

IF 5.5 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2025-06-16 DOI:10.1002/cjoc.70162

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引用次数: 0

摘要

利用简单单元整合引入新反应的思想，发现并开发了γ-羟基烯醛与1,3-二羰基化合物之间的新反应，生成了多功能化的5-烯基-3-羰基呋喃。在此过程中，γ-羟基被证明发挥了关键的邻基效应，促进了最初生成的2h -吡喃中间体向目标呋喃酮的开环异构化。Ma等人在1643-1650页的文章中讨论了更多细节。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Inside Cover Picture

With the idea of simple units integration to introduce new reactivities, a novel reaction between γ-hydroxyl enals and 1,3-dicarbonyl compounds has been discovered and developed, yielding polyfunctionalized 5-alkenyl-3-carbonylfurans. In this process, the γ-hydroxyl group is demonstrated to exert a critical neighboring group effect, facilitating the ring-opening isomerization of the initially generated 2H-pyran intermediate to the target furanones. More details are discussed in the article by Ma et al. on pages 1643—1650.

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来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.