Anna-Marie Lauermannová, Adéla Jiříčková, Martina Záleská, Milena Pavlíková, Adam Pivák, Ondřej Jankovský and Zbyšek Pavlík
{"title":"纳米改性moc基复合材料:氧化铝纳米片对材料微观结构和性能的影响","authors":"Anna-Marie Lauermannová, Adéla Jiříčková, Martina Záleská, Milena Pavlíková, Adam Pivák, Ondřej Jankovský and Zbyšek Pavlík","doi":"10.1039/D5MA00094G","DOIUrl":null,"url":null,"abstract":"<p >The presented study deals with the optimization of alumina nanosheets (<strong>ANS</strong>) content in magnesium oxychloride cement (MOC)-based construction composites filled with silica sand. The experimental setup was designed in such a way that the optimal content of <strong>ANS</strong> in these composites was determined while ensuring the highest possible values of mechanical parameters (compressive and flexural strength, and Young's dynamic modulus) while maintaining good water resistance of the prepared composite, which is a crucial parameter in terms of MOC-based materials. The designed composites were studied concerning the changes in their structure after the addition of <strong>ANS</strong>, especially in their porosity and density. The prepared composites were also examined in detail using scanning electron microscopy in order to show changes in their microstructure. It was revealed that the addition of 0.1 wt% of <strong>ANS</strong> was the most beneficial, causing an 8.4% increase in compressive strength, a 3.4% increase in flexural strength, and an 8.4% increase in the dynamic Young's modulus compared to the sample with no additives. On the other hand, the sample containing 0.5 wt% of <strong>ANS</strong> showed the best hygric properties with a water absorption coefficient of 3.21 kg m<small><sup>2</sup></small> s<small><sup>−1/2</sup></small> and 24-h water absorption of 68.3 kg m<small><sup>−3</sup></small> and the best resistance to water damage defined by the softening coefficient (78.3%) and the residual compressive strength (61.3 MPa) after 24 h immersion in water.</p>","PeriodicalId":18242,"journal":{"name":"Materials Advances","volume":" 12","pages":" 3817-3827"},"PeriodicalIF":4.7000,"publicationDate":"2025-05-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/ma/d5ma00094g?page=search","citationCount":"0","resultStr":"{\"title\":\"Nanoscale modification of MOC-based composites: the influence of alumina nanosheets on the microstructure and material properties\",\"authors\":\"Anna-Marie Lauermannová, Adéla Jiříčková, Martina Záleská, Milena Pavlíková, Adam Pivák, Ondřej Jankovský and Zbyšek Pavlík\",\"doi\":\"10.1039/D5MA00094G\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The presented study deals with the optimization of alumina nanosheets (<strong>ANS</strong>) content in magnesium oxychloride cement (MOC)-based construction composites filled with silica sand. 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引用次数: 0
摘要
研究了二氧化硅砂填充氯化镁水泥基建筑复合材料中氧化铝纳米片(ANS)含量的优化问题。实验设置的目的是确定复合材料中ANS的最佳含量,同时确保所制备的复合材料的力学参数(抗压和抗弯强度以及杨氏动态模量)尽可能高的值,同时保持良好的耐水性,这是moc基材料的关键参数。研究了所设计的复合材料在加入ANS后的结构变化,特别是孔隙率和密度的变化。利用扫描电子显微镜对制备的复合材料进行了详细的观察,以显示其微观结构的变化。结果表明,添加0.1 wt%的ANS是最有益的,与未添加添加剂的样品相比,其抗压强度增加8.4%,抗折强度增加3.4%,动态杨氏模量增加8.4%。另一方面,含有0.5 wt% ANS的样品表现出最佳的水力学性能,吸水系数为3.21 kg m2 s−1/2,24 h吸水率为68.3 kg m−3,浸水24 h后的软化系数为78.3%,残余抗压强度为61.3 MPa。
Nanoscale modification of MOC-based composites: the influence of alumina nanosheets on the microstructure and material properties
The presented study deals with the optimization of alumina nanosheets (ANS) content in magnesium oxychloride cement (MOC)-based construction composites filled with silica sand. The experimental setup was designed in such a way that the optimal content of ANS in these composites was determined while ensuring the highest possible values of mechanical parameters (compressive and flexural strength, and Young's dynamic modulus) while maintaining good water resistance of the prepared composite, which is a crucial parameter in terms of MOC-based materials. The designed composites were studied concerning the changes in their structure after the addition of ANS, especially in their porosity and density. The prepared composites were also examined in detail using scanning electron microscopy in order to show changes in their microstructure. It was revealed that the addition of 0.1 wt% of ANS was the most beneficial, causing an 8.4% increase in compressive strength, a 3.4% increase in flexural strength, and an 8.4% increase in the dynamic Young's modulus compared to the sample with no additives. On the other hand, the sample containing 0.5 wt% of ANS showed the best hygric properties with a water absorption coefficient of 3.21 kg m2 s−1/2 and 24-h water absorption of 68.3 kg m−3 and the best resistance to water damage defined by the softening coefficient (78.3%) and the residual compressive strength (61.3 MPa) after 24 h immersion in water.