CoCuOx-C电极的制备及其在废水处理中的催化性能

IF 5.5 3区材料科学 Q1 ELECTROCHEMISTRY

Electrochimica Acta Pub Date : 2025-06-14 DOI:10.1016/j.electacta.2025.146717

Lili Hu , Xiao Zhang , Xianheng Zhi , Yuling Zhang , Zhiqiang Zhang , Ming Li , Shuqin Wang

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引用次数: 0

摘要

传统阳极材料的高成本限制了电催化氧化技术的广泛应用。本文将HKUST-1 （CuOx-C）和ZIF-67 （CoOx-C）的炭化产物进行复合制备了一种低成本的CoCuOx-C电极材料。SEM、BET、XPS、CV和EIS等表征分析表明，CuOx-C/CoOx-C质量比为3:1的CoCuOx-C电极具有优异的电催化活性，对苯酚的降解效率为92.18%。复合材料表现出丰富的孔隙通道多样性，增强污染物的传质，提高电子传递效率，降低阻抗。CoCuOx-C电极通过在其表面产生丰富的羟基自由基（·OH），有效地降解污染物。本研究为提高电催化氧化技术的经济可行性提供了重要的策略。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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Preparation and catalytic performance of CoCuOx-C electrodes in wastewater treatment

The high costs of conventional anode materials constrain the widespread implementation of electrocatalytic oxidation technologies. The carbonized products of HKUST-1 (CuOx-C) and ZIF-67 (CoOx-C) were composited to fabricate a cost-effective CoCuOx-C electrode material in this work. Characterization analyses including SEM, BET, XPS, CV, and EIS demonstrated that the CoCuOx-C electrode with a CuOx-C/CoOx-C mass ratio of 3:1 exhibited superior electrocatalytic activity, achieving a phenol degradation efficiency of 92.18 %. The composite material displayed enriched pore channel diversity, enhanced mass transfer of pollutants, improved electron transport efficiency, and reduced impedance. The CoCuOx-C electrode efficiently degraded pollutants through the generation of abundant hydroxyl radicals (·OH) on its surface. This study provides a significant strategy for improving the economic feasibility of electrocatalytic oxidation technology.

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来源期刊

Electrochimica Acta 工程技术-电化学

CiteScore

11.30

自引率

6.10%

发文量

1634

审稿时长

41 days

期刊介绍： Electrochimica Acta is an international journal. It is intended for the publication of both original work and reviews in the field of electrochemistry. Electrochemistry should be interpreted to mean any of the research fields covered by the Divisions of the International Society of Electrochemistry listed below, as well as emerging scientific domains covered by ISE New Topics Committee.