提高PVC生产技术性能:基于wep的能源和水评估。

IF 4.7 3区 工程技术 Q1 POLYMER SCIENCE
Polymers Pub Date : 2025-06-04 DOI:10.3390/polym17111561
Rolando Manuel Guardo-Ruiz, Linda Mychell Puello-Castellón, Rodrigo Ortega-Toro, Eduardo Andrés Aguilar-Vásquez, Ángel Darío González-Delgado
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引用次数: 0

摘要

聚氯乙烯(PVC)是最广泛使用的聚合物之一,由于其物理性质和多功能性。悬浮法的耗水量是影响竞争力的关键问题。在这种情况下,本研究通过直接循环利用实现水整合,目的是尽量减少淡水消耗和废水产生。利用源汇图生成循环水管网,并利用软件对综合过程进行仿真。从模拟数据出发,采用水-能源-产品(water-energy-product, WEP)分析方法对工艺性能进行评价,并对水、能源和产品的可持续性指标进行评价。分步用水量和产废水比指标分别提高到51.1%和55.0%,而非一体化工艺的分步用水量和产废水比指标分别为41%和54%,显示出用水效率的提高和成本的降低。由于未反应VCM的有效回收,未反应物料的回用指数达到100%,生产收率达到99.8%。天然气的使用和能源整合使TCE、NGCI和EECI指标表现最佳。然而,由于水循环热控设备的能量需求,ESI指标较高(3.59 MJ/t)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Enhancing Technical Performance of PVC Production: A WEP-Based Energy and Water Assessment.

Polyvinyl chloride (PVC) is one of the most widely used polymers due to its physical properties and versatility. Water consumption of the suspension method is a critical issue that hinders competitiveness. In that case, this study implements water integration through direct recycling, with the aim of minimizing both freshwater consumption and wastewater generation. The source-sink diagram was used to generate the recycled water network, and the integrated process was simulated using software. From simulation data, the water-energy-product (WEP) analysis method was used to assess the process performance, and sustainability indicators for water, energy, and product were evaluated. Fractional water consumption and wastewater production ratio indicators increased to 51.1% and 55.0%, compared to 41% and 54% in the non-integrated process, showing improved water efficiency and cost reduction. The unreacted material reuse index reached 100%, while the production yield was 99.8%, due to effective recycling of unreacted VCM. The use of natural gas and energy integration led to optimal performance in TCE, NGCI, and EECI indicators. However, the ESI indicator was high (3.59 MJ/t) due to energy demands from thermal control equipment for water recirculation.

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来源期刊
Polymers
Polymers POLYMER SCIENCE-
CiteScore
8.00
自引率
16.00%
发文量
4697
审稿时长
1.3 months
期刊介绍: Polymers (ISSN 2073-4360) is an international, open access journal of polymer science. It publishes research papers, short communications and review papers. Our aim is to encourage scientists to publish their experimental and theoretical results in as much detail as possible. Therefore, there is no restriction on the length of the papers. The full experimental details must be provided so that the results can be reproduced. Polymers provides an interdisciplinary forum for publishing papers which advance the fields of (i) polymerization methods, (ii) theory, simulation, and modeling, (iii) understanding of new physical phenomena, (iv) advances in characterization techniques, and (v) harnessing of self-assembly and biological strategies for producing complex multifunctional structures.
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