线弧定向能沉积Mg-9Gd-3Y-2Zn-0.5Zr合金的组织演变及其与力学性能和腐蚀行为的关系

IF 4.8 2区 材料科学 Q1 MATERIALS SCIENCE, CHARACTERIZATION & TESTING
Jikang Fan , Baihao Cai , Jie Li , Pengfei Gao , Dongqing Yang , Yong Peng , Kehong Wang
{"title":"线弧定向能沉积Mg-9Gd-3Y-2Zn-0.5Zr合金的组织演变及其与力学性能和腐蚀行为的关系","authors":"Jikang Fan ,&nbsp;Baihao Cai ,&nbsp;Jie Li ,&nbsp;Pengfei Gao ,&nbsp;Dongqing Yang ,&nbsp;Yong Peng ,&nbsp;Kehong Wang","doi":"10.1016/j.matchar.2025.115262","DOIUrl":null,"url":null,"abstract":"<div><div>High-efficiency monolithic forming of large and complex components of Mg-RE (rare-earth) alloys using wire-arc additive manufacturing technology has been attracting much attention. In this work, a novel Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K) alloy component was prepared via wire-arc directed energy deposition (WA-DED) technology. The microstructure, mechanical properties, and corrosion behavior of both the as-built and heat-treated samples were comprehensively analyzed. The results showed that the as-deposited alloy was mainly composed of equiaxed grains, eutectic (Mg, Zn)<sub>3</sub>(Gd, Y) phases, stacking faults (SFs), and RE-rich phases. The specimen exhibits layered features characterized by alternating distributed coarse grains (CG) and fine grains (FG), low texture strength, and isotropic mechanical properties. After solution-aging treatment (520 °C × 8 h + 200 °C × 10 h), the eutectic phase and SFs transformed into the long-period stacking orders (LPSO) structures. The ultimate tensile strength (UTS) of 279 MPa, yield strength (YS) of 141 MPa, and elongation (EL) of 18.7 % in the TD were obtained at room temperature (RT). Grain boundary strengthening and LPSO strengthening play an essential role in enhancing alloy properties. The electrochemical test was carried out in 3.5 wt% NaCl solution revealed that the T6-treated samples exhibited enhanced corrosion resistance compared to the as-deposited samples, which could be attributed to the corrosion barrier effect of the lamellar LPSO structure and X phase.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"227 ","pages":"Article 115262"},"PeriodicalIF":4.8000,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructure evolution and its correlations with mechanical properties and corrosion behavior of Mg-9Gd-3Y-2Zn-0.5Zr alloy fabricated by wire-arc directed energy deposition\",\"authors\":\"Jikang Fan ,&nbsp;Baihao Cai ,&nbsp;Jie Li ,&nbsp;Pengfei Gao ,&nbsp;Dongqing Yang ,&nbsp;Yong Peng ,&nbsp;Kehong Wang\",\"doi\":\"10.1016/j.matchar.2025.115262\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>High-efficiency monolithic forming of large and complex components of Mg-RE (rare-earth) alloys using wire-arc additive manufacturing technology has been attracting much attention. In this work, a novel Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K) alloy component was prepared via wire-arc directed energy deposition (WA-DED) technology. The microstructure, mechanical properties, and corrosion behavior of both the as-built and heat-treated samples were comprehensively analyzed. The results showed that the as-deposited alloy was mainly composed of equiaxed grains, eutectic (Mg, Zn)<sub>3</sub>(Gd, Y) phases, stacking faults (SFs), and RE-rich phases. The specimen exhibits layered features characterized by alternating distributed coarse grains (CG) and fine grains (FG), low texture strength, and isotropic mechanical properties. After solution-aging treatment (520 °C × 8 h + 200 °C × 10 h), the eutectic phase and SFs transformed into the long-period stacking orders (LPSO) structures. The ultimate tensile strength (UTS) of 279 MPa, yield strength (YS) of 141 MPa, and elongation (EL) of 18.7 % in the TD were obtained at room temperature (RT). Grain boundary strengthening and LPSO strengthening play an essential role in enhancing alloy properties. The electrochemical test was carried out in 3.5 wt% NaCl solution revealed that the T6-treated samples exhibited enhanced corrosion resistance compared to the as-deposited samples, which could be attributed to the corrosion barrier effect of the lamellar LPSO structure and X phase.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"227 \",\"pages\":\"Article 115262\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-06-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325005510\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325005510","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
引用次数: 0

摘要

利用线弧增材制造技术高效整体成形大型复杂部件的Mg-RE(稀土)合金一直备受关注。本文采用线弧定向能沉积(WA-DED)技术制备了新型Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K)合金部件。综合分析了铸态和热处理试样的显微组织、力学性能和腐蚀行为。结果表明:沉积态合金主要由等轴晶、共晶(Mg, Zn)、共晶(Gd, Y)相、层错(SFs)和富re相组成;试样呈现出粗细晶粒交替分布的层状特征,织构强度低,力学性能各向同性。固溶时效处理(520°C × 8 h + 200°C × 10 h)后,共晶相和sf转变为长周期堆积顺序(LPSO)结构。室温下,合金的极限抗拉强度为279 MPa,屈服强度为141 MPa,伸长率为18.7%。晶界强化和LPSO强化对合金性能的提高起着至关重要的作用。在3.5 wt% NaCl溶液中进行的电化学测试表明,与沉积样品相比,t6处理后的样品具有更强的耐腐蚀性,这可能是由于层状LPSO结构和X相的腐蚀屏障作用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Microstructure evolution and its correlations with mechanical properties and corrosion behavior of Mg-9Gd-3Y-2Zn-0.5Zr alloy fabricated by wire-arc directed energy deposition
High-efficiency monolithic forming of large and complex components of Mg-RE (rare-earth) alloys using wire-arc additive manufacturing technology has been attracting much attention. In this work, a novel Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K) alloy component was prepared via wire-arc directed energy deposition (WA-DED) technology. The microstructure, mechanical properties, and corrosion behavior of both the as-built and heat-treated samples were comprehensively analyzed. The results showed that the as-deposited alloy was mainly composed of equiaxed grains, eutectic (Mg, Zn)3(Gd, Y) phases, stacking faults (SFs), and RE-rich phases. The specimen exhibits layered features characterized by alternating distributed coarse grains (CG) and fine grains (FG), low texture strength, and isotropic mechanical properties. After solution-aging treatment (520 °C × 8 h + 200 °C × 10 h), the eutectic phase and SFs transformed into the long-period stacking orders (LPSO) structures. The ultimate tensile strength (UTS) of 279 MPa, yield strength (YS) of 141 MPa, and elongation (EL) of 18.7 % in the TD were obtained at room temperature (RT). Grain boundary strengthening and LPSO strengthening play an essential role in enhancing alloy properties. The electrochemical test was carried out in 3.5 wt% NaCl solution revealed that the T6-treated samples exhibited enhanced corrosion resistance compared to the as-deposited samples, which could be attributed to the corrosion barrier effect of the lamellar LPSO structure and X phase.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Materials Characterization
Materials Characterization 工程技术-材料科学:表征与测试
CiteScore
7.60
自引率
8.50%
发文量
746
审稿时长
36 days
期刊介绍: Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials. The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal. The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include: Metals & Alloys Ceramics Nanomaterials Biomedical materials Optical materials Composites Natural Materials.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信