Jikang Fan , Baihao Cai , Jie Li , Pengfei Gao , Dongqing Yang , Yong Peng , Kehong Wang
{"title":"线弧定向能沉积Mg-9Gd-3Y-2Zn-0.5Zr合金的组织演变及其与力学性能和腐蚀行为的关系","authors":"Jikang Fan , Baihao Cai , Jie Li , Pengfei Gao , Dongqing Yang , Yong Peng , Kehong Wang","doi":"10.1016/j.matchar.2025.115262","DOIUrl":null,"url":null,"abstract":"<div><div>High-efficiency monolithic forming of large and complex components of Mg-RE (rare-earth) alloys using wire-arc additive manufacturing technology has been attracting much attention. In this work, a novel Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K) alloy component was prepared via wire-arc directed energy deposition (WA-DED) technology. The microstructure, mechanical properties, and corrosion behavior of both the as-built and heat-treated samples were comprehensively analyzed. The results showed that the as-deposited alloy was mainly composed of equiaxed grains, eutectic (Mg, Zn)<sub>3</sub>(Gd, Y) phases, stacking faults (SFs), and RE-rich phases. The specimen exhibits layered features characterized by alternating distributed coarse grains (CG) and fine grains (FG), low texture strength, and isotropic mechanical properties. After solution-aging treatment (520 °C × 8 h + 200 °C × 10 h), the eutectic phase and SFs transformed into the long-period stacking orders (LPSO) structures. The ultimate tensile strength (UTS) of 279 MPa, yield strength (YS) of 141 MPa, and elongation (EL) of 18.7 % in the TD were obtained at room temperature (RT). Grain boundary strengthening and LPSO strengthening play an essential role in enhancing alloy properties. The electrochemical test was carried out in 3.5 wt% NaCl solution revealed that the T6-treated samples exhibited enhanced corrosion resistance compared to the as-deposited samples, which could be attributed to the corrosion barrier effect of the lamellar LPSO structure and X phase.</div></div>","PeriodicalId":18727,"journal":{"name":"Materials Characterization","volume":"227 ","pages":"Article 115262"},"PeriodicalIF":4.8000,"publicationDate":"2025-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Microstructure evolution and its correlations with mechanical properties and corrosion behavior of Mg-9Gd-3Y-2Zn-0.5Zr alloy fabricated by wire-arc directed energy deposition\",\"authors\":\"Jikang Fan , Baihao Cai , Jie Li , Pengfei Gao , Dongqing Yang , Yong Peng , Kehong Wang\",\"doi\":\"10.1016/j.matchar.2025.115262\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>High-efficiency monolithic forming of large and complex components of Mg-RE (rare-earth) alloys using wire-arc additive manufacturing technology has been attracting much attention. In this work, a novel Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K) alloy component was prepared via wire-arc directed energy deposition (WA-DED) technology. The microstructure, mechanical properties, and corrosion behavior of both the as-built and heat-treated samples were comprehensively analyzed. The results showed that the as-deposited alloy was mainly composed of equiaxed grains, eutectic (Mg, Zn)<sub>3</sub>(Gd, Y) phases, stacking faults (SFs), and RE-rich phases. The specimen exhibits layered features characterized by alternating distributed coarse grains (CG) and fine grains (FG), low texture strength, and isotropic mechanical properties. After solution-aging treatment (520 °C × 8 h + 200 °C × 10 h), the eutectic phase and SFs transformed into the long-period stacking orders (LPSO) structures. The ultimate tensile strength (UTS) of 279 MPa, yield strength (YS) of 141 MPa, and elongation (EL) of 18.7 % in the TD were obtained at room temperature (RT). Grain boundary strengthening and LPSO strengthening play an essential role in enhancing alloy properties. The electrochemical test was carried out in 3.5 wt% NaCl solution revealed that the T6-treated samples exhibited enhanced corrosion resistance compared to the as-deposited samples, which could be attributed to the corrosion barrier effect of the lamellar LPSO structure and X phase.</div></div>\",\"PeriodicalId\":18727,\"journal\":{\"name\":\"Materials Characterization\",\"volume\":\"227 \",\"pages\":\"Article 115262\"},\"PeriodicalIF\":4.8000,\"publicationDate\":\"2025-06-12\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Characterization\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S1044580325005510\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CHARACTERIZATION & TESTING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Characterization","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S1044580325005510","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CHARACTERIZATION & TESTING","Score":null,"Total":0}
Microstructure evolution and its correlations with mechanical properties and corrosion behavior of Mg-9Gd-3Y-2Zn-0.5Zr alloy fabricated by wire-arc directed energy deposition
High-efficiency monolithic forming of large and complex components of Mg-RE (rare-earth) alloys using wire-arc additive manufacturing technology has been attracting much attention. In this work, a novel Mg-9Gd-3Y-2Y-0.5Zr (wt%, GWZ932K) alloy component was prepared via wire-arc directed energy deposition (WA-DED) technology. The microstructure, mechanical properties, and corrosion behavior of both the as-built and heat-treated samples were comprehensively analyzed. The results showed that the as-deposited alloy was mainly composed of equiaxed grains, eutectic (Mg, Zn)3(Gd, Y) phases, stacking faults (SFs), and RE-rich phases. The specimen exhibits layered features characterized by alternating distributed coarse grains (CG) and fine grains (FG), low texture strength, and isotropic mechanical properties. After solution-aging treatment (520 °C × 8 h + 200 °C × 10 h), the eutectic phase and SFs transformed into the long-period stacking orders (LPSO) structures. The ultimate tensile strength (UTS) of 279 MPa, yield strength (YS) of 141 MPa, and elongation (EL) of 18.7 % in the TD were obtained at room temperature (RT). Grain boundary strengthening and LPSO strengthening play an essential role in enhancing alloy properties. The electrochemical test was carried out in 3.5 wt% NaCl solution revealed that the T6-treated samples exhibited enhanced corrosion resistance compared to the as-deposited samples, which could be attributed to the corrosion barrier effect of the lamellar LPSO structure and X phase.
期刊介绍:
Materials Characterization features original articles and state-of-the-art reviews on theoretical and practical aspects of the structure and behaviour of materials.
The Journal focuses on all characterization techniques, including all forms of microscopy (light, electron, acoustic, etc.,) and analysis (especially microanalysis and surface analytical techniques). Developments in both this wide range of techniques and their application to the quantification of the microstructure of materials are essential facets of the Journal.
The Journal provides the Materials Scientist/Engineer with up-to-date information on many types of materials with an underlying theme of explaining the behavior of materials using novel approaches. Materials covered by the journal include:
Metals & Alloys
Ceramics
Nanomaterials
Biomedical materials
Optical materials
Composites
Natural Materials.