串联磷二硫基化/烯丙醇与P4S10和醇重排构建烯丙基磷二硫代酸酯

IF 3.6 2区化学 Q1 CHEMISTRY, ORGANIC

Journal of Organic Chemistry Pub Date : 2025-05-29 DOI:10.1021/acs.joc.5c0076110.1021/acs.joc.5c00761

Jian Huang, Yingjie Wang, Yufen Lv, Xiaohui Zhao, Zu-Li Wang, Wei Wei* and Dong Yi*,

引用次数: 0

摘要

本文提出了一种无添加剂合成烯丙基磷二硫代酸酯的方法，该方法是将烯丙醇与P4S10和醇进行串联磷二硫代酸/重排。该反应在温和的条件下进行，并提供了一个实用的方案，以制备一系列中至高产率的烯丙基二硫代磷酸酯。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Tandem Phosphorodithiolation/Rearrangement of Allylic Alcohols with P4S10 and Alcohols to Construct Allylic Phosphorodithioates

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Tandem Phosphorodithiolation/Rearrangement of Allylic Alcohols with P4S10 and Alcohols to Construct Allylic Phosphorodithioates

An additive-free approach has been developed for the synthesis of allylic phosphorodithioates through tandem phosphorodithiolation/rearrangement of allylic alcohols with P₄S₁₀ and alcohols. The reaction proceeds under mild conditions and provides a practical protocol to prepare a series of allylic phosphorodithioates in moderate to good yields.

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来源期刊

Journal of Organic Chemistry 化学-有机化学

CiteScore

6.20

自引率

11.10%

发文量

1467

审稿时长

2 months

期刊介绍： Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.