冷等离子体修饰h-BN纳米流体的分散稳定性和摩擦学性能。

IF 4.4 3区 材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Nanomaterials Pub Date : 2025-06-05 DOI:10.3390/nano15110874
Zhenjing Duan, Ziheng Wang, Yishuai Jia, Shuaishuai Wang, Peng Bian, Ji Tan, Jinlong Song, Xin Liu
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引用次数: 0

摘要

h-BN球形纳米颗粒,被称为白色石墨烯,具有良好的抗磨性能,使用寿命长,化学惰性和稳定性,作为纳米流体的固体添加剂,具有优越的润滑性能。然而,h-BN纳米颗粒在纳米流体中的分散稳定性差是制约其应用的瓶颈。目前,为了制备具有良好分散稳定性的氢氮化硼纳米流体,本研究提出了对氢氮化硼纳米粒子进行冷等离子体修饰。本研究分别制备了添加表面活性剂的h-BN纳米流体(SNL)、以N2为工作气体的CP改性h-BN纳米流体(CP(N2)NL)和以O2为工作气体的CP改性h-BN纳米流体(CP(O2)NL)。利用x射线光电子能谱(XPS)分析了cp改性h-BN纳米流体的分散稳定性机理,并通过纳米流体静态观察、运动粘度和传热性能分析了cp改性h-BN纳米流体的性能。最后,通过摩擦磨损实验,从摩擦系数、三维表面形貌、表面粗糙度(Sa)、划痕和微观形貌等方面进一步分析了h-BN纳米流体的摩擦学性能。结果表明,cp改性的h- bn纳米流体具有优异的分散悬浮稳定性,可静置336 h以上;cp改性的h- bn纳米流体具有稳定的减摩、抗磨和传热性能,沉淀24 h前后h- bn纳米流体的摩擦系数约为0.66。与纯棉籽油(CO)相比,样品的Sa值降低了31.6 ~ 49.2%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Dispersion Stability and Tribological Properties of Cold Plasma-Modified h-BN Nanofluid.

h-BN spherical nanoparticles, known as white graphene, have good anti-wear properties, long service life, chemical inertness, and stability, which provide superior lubricating performance as a solid additive item to nanofluids. However, the poor dispersion stability of h-BN nanoparticles in nanofluids is a bottleneck that restricts their application. Currently, to prepare h-BN nanofluids with good dispersion stability, a cold plasma (CP) modification of h-BN nanoparticles is proposed in this study. In this research, h-BN nanofluid with added surfactant (SNL), CP-modified h-BN nanofluid with N2 as the working gas (CP(N2)NL), and CP-modified h-BN nanofluid with O2 as the working gas (CP(O2)NL) were prepared, separately. The mechanism of the dispersion stability of CP-modified h-BN nanofluid was analyzed using X-ray photoelectron spectroscopy (XPS), and the performance of CP-modified nanofluid was analyzed based on static observation of nanofluid, kinematic viscosity, and heat transfer properties. Finally, friction and wear experiments were conducted to further analyze the tribological performance of h-BN nanofluids based on the coefficient of friction, 3D surface morphology, surface roughness (Sa), scratches, and micro-morphology. The results show that CP-modified h-BN nanofluid has excellent dispersed suspension stability and can be statically placed for more than 336 h. The CP-modified h-BN nanofluid showed stable friction-reducing, anti-wear, and heat transfer performance, in which the coefficient of friction of h-BN nanofluid was about 0.66 before and after 24 h of settling. The Sa value of the sample was reduced by 31.6-49.2% in comparison with pure cottonseed oil (CO).

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来源期刊
Nanomaterials
Nanomaterials NANOSCIENCE & NANOTECHNOLOGY-MATERIALS SCIENCE, MULTIDISCIPLINARY
CiteScore
8.50
自引率
9.40%
发文量
3841
审稿时长
14.22 days
期刊介绍: Nanomaterials (ISSN 2076-4991) is an international and interdisciplinary scholarly open access journal. It publishes reviews, regular research papers, communications, and short notes that are relevant to any field of study that involves nanomaterials, with respect to their science and application. Thus, theoretical and experimental articles will be accepted, along with articles that deal with the synthesis and use of nanomaterials. Articles that synthesize information from multiple fields, and which place discoveries within a broader context, will be preferred. There is no restriction on the length of the papers. Our aim is to encourage scientists to publish their experimental and theoretical research in as much detail as possible. Full experimental or methodical details, or both, must be provided for research articles. Computed data or files regarding the full details of the experimental procedure, if unable to be published in a normal way, can be deposited as supplementary material. Nanomaterials is dedicated to a high scientific standard. All manuscripts undergo a rigorous reviewing process and decisions are based on the recommendations of independent reviewers.
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