Weirong Xie, Jin Zhang, Pan Wang, Ya Sun, Jing Li, Jianing Xu, Di Zhang and Han Zhou*,
{"title":"用于动态辐射温度调节和能量储存的柔性电驱动纳米光子器件。","authors":"Weirong Xie, Jin Zhang, Pan Wang, Ya Sun, Jing Li, Jianing Xu, Di Zhang and Han Zhou*, ","doi":"10.1021/acs.nanolett.5c02289","DOIUrl":null,"url":null,"abstract":"<p >Dynamic thermal management is useful for maintaining personal thermal comfort. However, integrating multifunctionalities into flexible thermal management device remains challenging. Inspired by color modulation mechanisms of cephalopod skin, we demonstrate a flexible electro-driven nanophotonic (FEN) device with dual-functionalities of dynamic radiative thermoregulation and all-time energy supply. Flexibility is achieved by depositing nanoscaled silicon film onto a flexible nanoporous separator. High IR emissivity regulation from 0.85 (cooling mode) to 0.19 (heating mode) at 8–13 μm is achieved, accompanied by an apparent temperature modulation of 13 °C. Besides, integrated energy storage performance shows a superior areal capacity of ∼0.35 mAh cm<sup>–2</sup> and a Coulombic efficiency of ∼70%. Additionally, we propose a tunable mechanism of electro-optical-thermal conversion via the reversible insertion/extraction of lithium ions in silicon film. We believe that such flexibility and multifunctionality will position our FEN device as a versatile platform for next-generation personal thermal management, energy storage systems, and information encryption technologies.</p>","PeriodicalId":53,"journal":{"name":"Nano Letters","volume":"25 25","pages":"10193–10201"},"PeriodicalIF":9.1000,"publicationDate":"2025-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Flexible Electro-Driven Nanophotonic Device for Dynamic Radiative Thermoregulation and Energy Storage\",\"authors\":\"Weirong Xie, Jin Zhang, Pan Wang, Ya Sun, Jing Li, Jianing Xu, Di Zhang and Han Zhou*, \",\"doi\":\"10.1021/acs.nanolett.5c02289\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Dynamic thermal management is useful for maintaining personal thermal comfort. However, integrating multifunctionalities into flexible thermal management device remains challenging. Inspired by color modulation mechanisms of cephalopod skin, we demonstrate a flexible electro-driven nanophotonic (FEN) device with dual-functionalities of dynamic radiative thermoregulation and all-time energy supply. Flexibility is achieved by depositing nanoscaled silicon film onto a flexible nanoporous separator. High IR emissivity regulation from 0.85 (cooling mode) to 0.19 (heating mode) at 8–13 μm is achieved, accompanied by an apparent temperature modulation of 13 °C. Besides, integrated energy storage performance shows a superior areal capacity of ∼0.35 mAh cm<sup>–2</sup> and a Coulombic efficiency of ∼70%. Additionally, we propose a tunable mechanism of electro-optical-thermal conversion via the reversible insertion/extraction of lithium ions in silicon film. We believe that such flexibility and multifunctionality will position our FEN device as a versatile platform for next-generation personal thermal management, energy storage systems, and information encryption technologies.</p>\",\"PeriodicalId\":53,\"journal\":{\"name\":\"Nano Letters\",\"volume\":\"25 25\",\"pages\":\"10193–10201\"},\"PeriodicalIF\":9.1000,\"publicationDate\":\"2025-06-10\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Nano Letters\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.nanolett.5c02289\",\"RegionNum\":1,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Nano Letters","FirstCategoryId":"88","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.nanolett.5c02289","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
动态热管理对保持个人热舒适是有用的。然而，将多功能集成到柔性热管理设备中仍然具有挑战性。受头足类动物皮肤颜色调制机制的启发，我们展示了一种柔性电驱动纳米光子（FEN）装置，具有动态辐射温度调节和全天候能量供应的双重功能。柔性是通过在柔性纳米孔分离器上沉积纳米级硅膜来实现的。在8-13 μm范围内实现了从0.85（冷却模式）到0.19（加热模式）的高红外发射率调节，并伴有13°C的表观温度调制。此外，集成储能性能显示出优越的面容量（~ 0.35 mAh cm-2）和库仑效率（~ 70%）。此外，我们提出了一种可调的电光热转换机制，通过可逆的锂离子在硅膜中的插入/提取。我们相信，这种灵活性和多功能性将使我们的FEN设备成为下一代个人热管理、能量存储系统和信息加密技术的通用平台。
Flexible Electro-Driven Nanophotonic Device for Dynamic Radiative Thermoregulation and Energy Storage
Dynamic thermal management is useful for maintaining personal thermal comfort. However, integrating multifunctionalities into flexible thermal management device remains challenging. Inspired by color modulation mechanisms of cephalopod skin, we demonstrate a flexible electro-driven nanophotonic (FEN) device with dual-functionalities of dynamic radiative thermoregulation and all-time energy supply. Flexibility is achieved by depositing nanoscaled silicon film onto a flexible nanoporous separator. High IR emissivity regulation from 0.85 (cooling mode) to 0.19 (heating mode) at 8–13 μm is achieved, accompanied by an apparent temperature modulation of 13 °C. Besides, integrated energy storage performance shows a superior areal capacity of ∼0.35 mAh cm–2 and a Coulombic efficiency of ∼70%. Additionally, we propose a tunable mechanism of electro-optical-thermal conversion via the reversible insertion/extraction of lithium ions in silicon film. We believe that such flexibility and multifunctionality will position our FEN device as a versatile platform for next-generation personal thermal management, energy storage systems, and information encryption technologies.
期刊介绍：
Nano Letters serves as a dynamic platform for promptly disseminating original results in fundamental, applied, and emerging research across all facets of nanoscience and nanotechnology. A pivotal criterion for inclusion within Nano Letters is the convergence of at least two different areas or disciplines, ensuring a rich interdisciplinary scope. The journal is dedicated to fostering exploration in diverse areas, including:
- Experimental and theoretical findings on physical, chemical, and biological phenomena at the nanoscale
- Synthesis, characterization, and processing of organic, inorganic, polymer, and hybrid nanomaterials through physical, chemical, and biological methodologies
- Modeling and simulation of synthetic, assembly, and interaction processes
- Realization of integrated nanostructures and nano-engineered devices exhibiting advanced performance
- Applications of nanoscale materials in living and environmental systems
Nano Letters is committed to advancing and showcasing groundbreaking research that intersects various domains, fostering innovation and collaboration in the ever-evolving field of nanoscience and nanotechnology.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
