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不稳定环丙烯-1-羧酸酯的合成与分离

IF 4.2 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Chemical Communications Pub Date : 2025-06-10 DOI:10.1039/d5cc02673c
Jiahao Ling , Jiabao Tian , Xinhai Zhu , Lei Zhou
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引用次数: 0

摘要

通过蓝光促进的乙烯基重偶氮化合物光解制备和分离了稳定性较差的受体型环丙烯。动力学测量表明，它们的半衰期受浓度、温度和溶剂的影响。
本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and isolation of less stable cyclopropene-1-carboxylates†

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Synthesis and isolation of less stable cyclopropene-1-carboxylates†
Less stable acceptor-type cyclopropenes are prepared and isolated via blue light-promoted photolysis of vinyldiazo compounds. The kinetic measurements indicated that their half-lives were influenced by the concentration, temperature and solvent.
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来源期刊
Chemical Communications
Chemical Communications 化学-化学综合
CiteScore
8.60
自引率
4.10%
发文量
2705
审稿时长
1.4 months
期刊介绍： ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.
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