红光和超硅烷：一种新的氢官能化和吉斯反应途径。

IF 3.3 Q2 CHEMISTRY, MULTIDISCIPLINARY

ACS Organic & Inorganic Au Pub Date : 2025-05-10 eCollection Date: 2025-06-04 DOI:10.1021/acsorginorgau.5c00032

Aakanksha Gurawa, Marc Taillefer, Alexis Prieto

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引用次数: 0

摘要

在此，我们描述了硅烷在深红色照射下的光氧化还原活化，有或没有锇基光催化剂产生硅基自由基。这些自由基被进一步用于实现以前在红光光谱区域未被发现的各种反应，如硅氢化、氢磺化和吉斯反应。总的来说，开发的深红色协议允许制备各种高价值分子。

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Red Light and Supersilane: A Novel Pathway for Hydrofunctionalizations and Giese Reactions.

Herein, we describe the photoredox activation of silanes under deep-red irradiation with or without osmium-based photocatalysts to generate silyl radicals. These radicals were further employed for achieving various reactivities previously unexplored in the red-light spectral region, such as hydrosilylation, hydrosulfonylation, and Giese reaction. Overall, the developed deep-red protocols allow for the preparation of a diverse array of high-value molecules.

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来源期刊

ACS Organic & Inorganic Au 有机化学、无机化学-

CiteScore

4.10

自引率

0.00%

发文量

期刊介绍： ACS Organic & Inorganic Au is an open access journal that publishes original experimental and theoretical/computational studies on organic organometallic inorganic crystal growth and engineering and organic process chemistry. Short letters comprehensive articles reviews and perspectives are welcome on topics that include:Organic chemistry Organometallic chemistry Inorganic Chemistry and Organic Process Chemistry.