4-芳基-1,2,3-噻二唑作为二芳基硫代盐与二芳基碘鎓盐反应的替代物：一种无过渡金属的烷基芳基硫化物合成途径。

IF 2.7 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-04-22 DOI:10.1039/d5ob00576k

Polina Zaikina , Dmitry Bugaenko , Alexander Karchava

引用次数: 0

摘要

利用易得的1,2,3-噻二唑作为瞬态炔基硫代阴离子的替代物和二芳基硫鎓盐作为芳基化剂，首次在无过渡金属的条件下通过C(sp2)-S键合成炔基芳基硫化物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

4-Aryl-1,2,3-thiadiazoles as alkynyl thiolate surrogates in the reactions with diaryliodonium salts: a transition-metal-free route to alkynyl aryl sulfides†

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4-Aryl-1,2,3-thiadiazoles as alkynyl thiolate surrogates in the reactions with diaryliodonium salts: a transition-metal-free route to alkynyl aryl sulfides†

The use of readily available 1,2,3-thiadiazoles as surrogates of transient alkynyl thiolate anions and diaryliodonium salts as arylating agents allowed for the first time the synthesis of alkynyl aryl sulfides via C(sp²)–S bond formation under transition metal-free conditions.

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来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.