电化学储能材料的发展与现状

IF 4.3 3区材料科学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Journal of Physics and Chemistry of Solids Pub Date : 2025-06-04 DOI:10.1016/j.jpcs.2025.112917

Shucun Li , Miao Zhu , Peng Wang , xuejun Mo

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引用次数: 0

摘要

本文综述了电化学储能材料的发展现状，重点介绍了硫基电池、氧基电池和卤素基电池的最新进展。硫基电池具有理论容量高、成本低等优点，但面临多硫化物穿梭效应和锂枝晶生长等问题。氧基电池利用氧作为正极活性物质，但受到放电产物Li2O2不可逆分解和反应动力学缓慢的限制。卤素电池具有较高的安全性和成本效益，但受到锌枝晶和溴穿梭效应的限制。通过创新的材料设计和催化机制，这些电池在能量密度、循环寿命和成本方面取得了重大进展，但仍需要克服商业化的核心问题。

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Development and current status of electrochemical energy storage materials

This paper reviews the current development status of electrochemical energy storage materials, focusing on the latest progress of sulfur-based, oxygen-based, and halogen-based batteries. Sulfur-based batteries have the advantages of high theoretical capacity and low cost, but face issues such as polysulfide shuttle effect and lithium dendrite growth. Oxygen-based batteries utilize oxygen as the cathode active material, but are limited by the irreversible decomposition of discharge product Li₂O₂ and slow reaction kinetics. Halogen-based batteries have high safety and cost-effectiveness, but are limited by zinc dendrite and bromine shuttle effects. Through innovative material design and catalytic mechanisms, these batteries have made significant progress in energy density, cycle life, and cost, but still need to overcome core issues in commercialization.

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来源期刊

Journal of Physics and Chemistry of Solids 工程技术-化学综合

CiteScore

7.80

自引率

2.50%

发文量

605

审稿时长

40 days

期刊介绍： The Journal of Physics and Chemistry of Solids is a well-established international medium for publication of archival research in condensed matter and materials sciences. Areas of interest broadly include experimental and theoretical research on electronic, magnetic, spectroscopic and structural properties as well as the statistical mechanics and thermodynamics of materials. The focus is on gaining physical and chemical insight into the properties and potential applications of condensed matter systems. Within the broad scope of the journal, beyond regular contributions, the editors have identified submissions in the following areas of physics and chemistry of solids to be of special current interest to the journal: Low-dimensional systems Exotic states of quantum electron matter including topological phases Energy conversion and storage Interfaces, nanoparticles and catalysts.