异相催化剂在制备生物基平台化合物5-羟甲基糠醛中的应用。

IF 5.1 3区 生物学 Q1 BIOTECHNOLOGY & APPLIED MICROBIOLOGY
Yuyuan He, Jinrong Zhou, Han Li, Lin Deng, Jinnan Gao
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引用次数: 0

摘要

近年来,人们越来越关注从丰富的生物质资源中开发可再生能源和材料。5-羟甲基糠醛(HMF)由于其多用途的反应性,被认为是一种很有前途的合成增值化学品和材料的生物基平台化合物。HMF可由碳水化合物和各种原料生物质经酸水解反应直接合成。非均相催化剂因其环境友好、易于从反应混合物中分离、催化效率高、对设备的腐蚀性低等优点,在生物质转化中得到了突出的应用。本文系统地研究了利用多相催化剂从果糖、葡萄糖、纤维素和原料生物质合成HMF的反应途径和机制。然后介绍了以糠醛为原料,采用不同的催化方法制备呋喃二羧酸(FDCA)。FDCA是替代石油基聚对苯二甲酸酯的重要可降解生物材料单体。最后展望了HMF合成在不久的将来所面临的挑战和机遇。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Application of heterogeneous catalysts in the preparation of bio-based platform compound 5-hydroxymethylfurfural.

In recent years, there has been growing attention towards developing renewable energy and materials derived from abundant biomass resources. 5-Hydroxymethylfurfural (HMF) is recognized as a promising bio-based platform compound for synthesizing value-added chemicals and materials due to its versatile reactivity. HMF can be directly synthesized from carbohydrates and various raw biomass through the acid-hydrolysis reaction. Heterogeneous catalysts have gained prominence in biomass conversion owing to their environmental friendliness, facile separation from reaction mixtures, high catalytic efficiency, and reduced corrosivity toward equipment. This review systematically examines the reaction pathways and mechanisms involved in HMF synthesis from fructose, glucose, cellulose, and raw biomass using heterogeneous catalysts. Then we give an introduction to the preparation of furandicarboxylic acid (FDCA) from HMF with different catalytic methods. FDCA is an important degradable bio-material monomer for polyethylene furanoate to replace petroleum-based polyethylene terephthalate. This review ends with a prospect on the challenges and opportunities of HMF synthesis in the near future.

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来源期刊
Bioresources and Bioprocessing
Bioresources and Bioprocessing BIOTECHNOLOGY & APPLIED MICROBIOLOGY-
CiteScore
7.20
自引率
8.70%
发文量
118
审稿时长
13 weeks
期刊介绍: Bioresources and Bioprocessing (BIOB) is a peer-reviewed open access journal published under the brand SpringerOpen. BIOB aims at providing an international academic platform for exchanging views on and promoting research to support bioresource development, processing and utilization in a sustainable manner. As an application-oriented research journal, BIOB covers not only the application and management of bioresource technology but also the design and development of bioprocesses that will lead to new and sustainable production processes. BIOB publishes original and review articles on most topics relating to bioresource and bioprocess engineering, including: -Biochemical and microbiological engineering -Biocatalysis and biotransformation -Biosynthesis and metabolic engineering -Bioprocess and biosystems engineering -Bioenergy and biorefinery -Cell culture and biomedical engineering -Food, agricultural and marine biotechnology -Bioseparation and biopurification engineering -Bioremediation and environmental biotechnology
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