Franziska Flecken, Arjun Neyyathala, Toni Grell, Schirin Hanf
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引用次数: 0
摘要
通过独特的原位还原和氟化机制，由[Ni(MeCN)4](BF4)2和Ph2P（= O）─PPh2合成了空气和水稳定的Ni（PFPh2）配合物[Ni(PFPh2)4]，其中含有典型的不稳定的氟膦配体。在他们的研究文章（e202506271）中，Schirin Hanf et al.证明了其作为强大的Ni(0)源的实用性，并且与传统的[Ni(COD)2]相比，其在偶联反应中的催化活性更强。
Outside Front Cover: A Bench-stable Fluorophosphine Nickel(0) Complex and Its Catalytic Application (Angew. Chem. 24/2025)
The air- and water-stable Ni(0) complex [Ni(PFPh2)4] is obtained via a unique in-situ reduction and fluorination mechanism from [Ni(MeCN)4](BF4)2 and Ph2P(═O)─PPh2, incorporating typically unstable fluorophosphine ligands. In their Research Article (e202506271), Schirin Hanf et al. demonstrated its utility as a robust Ni(0) source, and showed its superior catalytic activity in coupling reactions compared to the conventional [Ni(COD)2].
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