{"title":"内页封面：通过Cu─O键长描述子优化铜酸盐上CO2电合成CH4的选择性。化学24/2025)","authors":"Yunze Xu, Yu Zhang, Hongyan Zhao, Lei Shi, Zhenbao Zhang, Xueyan Li, Zhen Xue, Heqing Jiang, Yongfa Zhu, Jiawei Zhu","doi":"10.1002/ange.202510022","DOIUrl":null,"url":null,"abstract":"<p>In their Research Article (e202503745), Jiawei Zhu and co-workers report a selectivity descriptor based on Cu─O bond length for screening highly selective cuprates toward CH<sub>4</sub> electrosynthesis. This descriptor reveals that CH<sub>4</sub> selectivity exhibits a volcano-shaped correlation with the Cu─O bond length, with the optimal value accessible at ∼1.951 Å. Using this descriptor, three new cuprates are predicted, demonstrating better performance compared to the reported Cu-based catalysts in acidic electrolytes.\n\n <figure>\n <div><picture>\n <source></source></picture><p></p>\n </div>\n </figure></p>","PeriodicalId":7803,"journal":{"name":"Angewandte Chemie","volume":"137 24","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510022","citationCount":"0","resultStr":"{\"title\":\"Inside Front Cover: Optimizing the Selectivity of CH4 Electrosynthesis from CO2 over Cuprates through Cu─O Bond Length Descriptor (Angew. Chem. 24/2025)\",\"authors\":\"Yunze Xu, Yu Zhang, Hongyan Zhao, Lei Shi, Zhenbao Zhang, Xueyan Li, Zhen Xue, Heqing Jiang, Yongfa Zhu, Jiawei Zhu\",\"doi\":\"10.1002/ange.202510022\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>In their Research Article (e202503745), Jiawei Zhu and co-workers report a selectivity descriptor based on Cu─O bond length for screening highly selective cuprates toward CH<sub>4</sub> electrosynthesis. This descriptor reveals that CH<sub>4</sub> selectivity exhibits a volcano-shaped correlation with the Cu─O bond length, with the optimal value accessible at ∼1.951 Å. Using this descriptor, three new cuprates are predicted, demonstrating better performance compared to the reported Cu-based catalysts in acidic electrolytes.\\n\\n <figure>\\n <div><picture>\\n <source></source></picture><p></p>\\n </div>\\n </figure></p>\",\"PeriodicalId\":7803,\"journal\":{\"name\":\"Angewandte Chemie\",\"volume\":\"137 24\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-05-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://onlinelibrary.wiley.com/doi/epdf/10.1002/ange.202510022\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Angewandte Chemie\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/ange.202510022\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Angewandte Chemie","FirstCategoryId":"1085","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/ange.202510022","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Inside Front Cover: Optimizing the Selectivity of CH4 Electrosynthesis from CO2 over Cuprates through Cu─O Bond Length Descriptor (Angew. Chem. 24/2025)
In their Research Article (e202503745), Jiawei Zhu and co-workers report a selectivity descriptor based on Cu─O bond length for screening highly selective cuprates toward CH4 electrosynthesis. This descriptor reveals that CH4 selectivity exhibits a volcano-shaped correlation with the Cu─O bond length, with the optimal value accessible at ∼1.951 Å. Using this descriptor, three new cuprates are predicted, demonstrating better performance compared to the reported Cu-based catalysts in acidic electrolytes.
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