Hai Li , Yang Li , Binglin Zheng , Jie Ding , Wentao Li , Changjian Wang
{"title":"氢-氨混合物爆炸特性研究:点火位置的影响","authors":"Hai Li , Yang Li , Binglin Zheng , Jie Ding , Wentao Li , Changjian Wang","doi":"10.1016/j.ijhydene.2025.05.366","DOIUrl":null,"url":null,"abstract":"<div><div>A series of experiments were conducted in a 0.125 m<sup>3</sup> cubic vessel to investigate the effects of ignition position on hydrogen-ammonia mixture. For top ignition, two obvious peaks of <em>P</em><sub>open</sub> and <em>P</em><sub>hel</sub> can be observed. <em>P</em><sub>open</sub> is around 14 kPa for all concentrations, while <em>P</em><sub>hel</sub> increases with the Hydrogen-ammonia mixture concentration. For center ignition, the appearance or disappearance of <em>P</em><sub>vib</sub> depends on the rate of reaction. Internal flame speed shows an upward trend when the <span><math><mrow><msub><mi>C</mi><msub><mrow><mi>N</mi><mi>H</mi></mrow><mn>3</mn></msub></msub></mrow></math></span> is between 15 % and 19 %, while the flame speed begins to decrease when the <span><math><mrow><msub><mi>C</mi><msub><mrow><mi>N</mi><mi>H</mi></mrow><mn>3</mn></msub></msub></mrow></math></span> exceeds 19 %. Compared to the top ignition and center ignition, bottom ignition takes the shortest time to reach the maximum displacement of the external flame due to the buoyancy of the ammonia flame. It can be found that the highest combustion efficiency occur for bottom ignition with <span><math><mrow><msub><mi>C</mi><msub><mrow><mi>N</mi><mi>H</mi></mrow><mn>3</mn></msub></msub></mrow></math></span> of 19 %.</div></div>","PeriodicalId":337,"journal":{"name":"International Journal of Hydrogen Energy","volume":"144 ","pages":"Pages 315-326"},"PeriodicalIF":8.1000,"publicationDate":"2025-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Investigation into the explosion characteristics of hydrogen-ammonia mixture: Effect of ignition position\",\"authors\":\"Hai Li , Yang Li , Binglin Zheng , Jie Ding , Wentao Li , Changjian Wang\",\"doi\":\"10.1016/j.ijhydene.2025.05.366\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of experiments were conducted in a 0.125 m<sup>3</sup> cubic vessel to investigate the effects of ignition position on hydrogen-ammonia mixture. For top ignition, two obvious peaks of <em>P</em><sub>open</sub> and <em>P</em><sub>hel</sub> can be observed. <em>P</em><sub>open</sub> is around 14 kPa for all concentrations, while <em>P</em><sub>hel</sub> increases with the Hydrogen-ammonia mixture concentration. For center ignition, the appearance or disappearance of <em>P</em><sub>vib</sub> depends on the rate of reaction. Internal flame speed shows an upward trend when the <span><math><mrow><msub><mi>C</mi><msub><mrow><mi>N</mi><mi>H</mi></mrow><mn>3</mn></msub></msub></mrow></math></span> is between 15 % and 19 %, while the flame speed begins to decrease when the <span><math><mrow><msub><mi>C</mi><msub><mrow><mi>N</mi><mi>H</mi></mrow><mn>3</mn></msub></msub></mrow></math></span> exceeds 19 %. Compared to the top ignition and center ignition, bottom ignition takes the shortest time to reach the maximum displacement of the external flame due to the buoyancy of the ammonia flame. It can be found that the highest combustion efficiency occur for bottom ignition with <span><math><mrow><msub><mi>C</mi><msub><mrow><mi>N</mi><mi>H</mi></mrow><mn>3</mn></msub></msub></mrow></math></span> of 19 %.</div></div>\",\"PeriodicalId\":337,\"journal\":{\"name\":\"International Journal of Hydrogen Energy\",\"volume\":\"144 \",\"pages\":\"Pages 315-326\"},\"PeriodicalIF\":8.1000,\"publicationDate\":\"2025-06-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Hydrogen Energy\",\"FirstCategoryId\":\"5\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0360319925026758\",\"RegionNum\":2,\"RegionCategory\":\"工程技术\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, PHYSICAL\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Hydrogen Energy","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0360319925026758","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
Investigation into the explosion characteristics of hydrogen-ammonia mixture: Effect of ignition position
A series of experiments were conducted in a 0.125 m3 cubic vessel to investigate the effects of ignition position on hydrogen-ammonia mixture. For top ignition, two obvious peaks of Popen and Phel can be observed. Popen is around 14 kPa for all concentrations, while Phel increases with the Hydrogen-ammonia mixture concentration. For center ignition, the appearance or disappearance of Pvib depends on the rate of reaction. Internal flame speed shows an upward trend when the is between 15 % and 19 %, while the flame speed begins to decrease when the exceeds 19 %. Compared to the top ignition and center ignition, bottom ignition takes the shortest time to reach the maximum displacement of the external flame due to the buoyancy of the ammonia flame. It can be found that the highest combustion efficiency occur for bottom ignition with of 19 %.
期刊介绍:
The objective of the International Journal of Hydrogen Energy is to facilitate the exchange of new ideas, technological advancements, and research findings in the field of Hydrogen Energy among scientists and engineers worldwide. This journal showcases original research, both analytical and experimental, covering various aspects of Hydrogen Energy. These include production, storage, transmission, utilization, enabling technologies, environmental impact, economic considerations, and global perspectives on hydrogen and its carriers such as NH3, CH4, alcohols, etc.
The utilization aspect encompasses various methods such as thermochemical (combustion), photochemical, electrochemical (fuel cells), and nuclear conversion of hydrogen, hydrogen isotopes, and hydrogen carriers into thermal, mechanical, and electrical energies. The applications of these energies can be found in transportation (including aerospace), industrial, commercial, and residential sectors.