铑催化邻碳硼烷的B(4)-H选择性硫代反应

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-06-04 DOI:10.1021/acs.inorgchem.5c00880

Qi-Jia Jiang, Ke Cao

{"title":"铑催化邻碳硼烷的B(4)-H选择性硫代反应","authors":"Qi-Jia Jiang, Ke Cao","doi":"10.1021/acs.inorgchem.5c00880","DOIUrl":null,"url":null,"abstract":"A rhodium-catalyzed universal protocol for selective chalcogenation of B(4)-H of o-carboranes with diaryl diselenides, diaryl disulfides, and diphenyl ditelluride has been developed for the first time. A series of B(4)-Se/S/Te-o-carborane derivatives decorated with various kinds of active groups have been synthesized with excellent yields and regioselectivity. Based on control experiments, a plausible mechanism involving radical and direct oxidative addition process is proposed. This work would be an important reference for the design of new reactions for the chalcogenation of boron clusters.","PeriodicalId":40,"journal":{"name":"Inorganic Chemistry","volume":"13 1","pages":""},"PeriodicalIF":4.7000,"publicationDate":"2025-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Rhodium-Catalyzed Selective Chalcogenation of B(4)-H of o-Carboranes\",\"authors\":\"Qi-Jia Jiang, Ke Cao\",\"doi\":\"10.1021/acs.inorgchem.5c00880\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A rhodium-catalyzed universal protocol for selective chalcogenation of B(4)-H of o-carboranes with diaryl diselenides, diaryl disulfides, and diphenyl ditelluride has been developed for the first time. A series of B(4)-Se/S/Te-o-carborane derivatives decorated with various kinds of active groups have been synthesized with excellent yields and regioselectivity. Based on control experiments, a plausible mechanism involving radical and direct oxidative addition process is proposed. This work would be an important reference for the design of new reactions for the chalcogenation of boron clusters.\",\"PeriodicalId\":40,\"journal\":{\"name\":\"Inorganic Chemistry\",\"volume\":\"13 1\",\"pages\":\"\"},\"PeriodicalIF\":4.7000,\"publicationDate\":\"2025-06-04\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganic Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1021/acs.inorgchem.5c00880\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1021/acs.inorgchem.5c00880","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

首次提出了一种铑催化邻碳硼烷B(4)-H与二芳基二硒化物、二芳基二硫化物和二苯基二碲化物选择性加硫的通用方案。合成了一系列具有多种活性基团修饰的B(4)-Se/S/ te -o-碳硼烷衍生物，具有优异的产率和区域选择性。在对照实验的基础上，提出了自由基和直接氧化加成的机理。本研究对设计硼团簇硫化反应具有重要的参考意义。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Rhodium-Catalyzed Selective Chalcogenation of B(4)-H of o-Carboranes

查看原文本刊更多论文

Rhodium-Catalyzed Selective Chalcogenation of B(4)-H of o-Carboranes

A rhodium-catalyzed universal protocol for selective chalcogenation of B(4)-H of o-carboranes with diaryl diselenides, diaryl disulfides, and diphenyl ditelluride has been developed for the first time. A series of B(4)-Se/S/Te-o-carborane derivatives decorated with various kinds of active groups have been synthesized with excellent yields and regioselectivity. Based on control experiments, a plausible mechanism involving radical and direct oxidative addition process is proposed. This work would be an important reference for the design of new reactions for the chalcogenation of boron clusters.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.