含能n -氟二硝基甲基杂环盐的合成与性能研究

IF 1.9 4区化学 Q3 CHEMISTRY, INORGANIC & NUCLEAR

Journal of Fluorine Chemistry Pub Date : 2025-05-27 DOI:10.1016/j.jfluchem.2025.110436

Andrei A. Gakh , Victor V. Semenov

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引用次数: 0

摘要

用稀释氟将相应的n -二硝基甲基杂环化合物亲电氟化，合成了一类新的能盐n -氟二硝基甲基杂环盐。这些盐是含有氟二硝基甲基部分直接与带正电的氮原子相连的化合物的罕见例子。进一步的改进可以与爆炸阴离子结合，如氰二硝基甲烷阴离子。尽管n -氟二硝基甲基杂环盐具有不同寻常的结构特征，但在环境条件下具有良好的热稳定性和化学稳定性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Synthesis and properties of energetic N-fluorodinitromethyl heterocyclic salts

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Synthesis and properties of energetic N-fluorodinitromethyl heterocyclic salts

The synthesis of a new class of energetic salts, N-fluorodinitromethyl heterocyclic salts, was accomplished by electrophilic fluorination of corresponding heterocyclic N-dinitromethyl ylides with diluted fluorine. These salts represent rare examples of compounds containing a fluorodinitromethyl moiety directly attached to a positively charged nitrogen atom. Further improvements can be achieved in combination with explosophoric anions, such as the cyanodinitromethanide anion. Despite their unusual structural features, N-fluorodinitromethyl heterocyclic salts have good thermal and chemical stability under ambient conditions.

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来源期刊

Journal of Fluorine Chemistry 化学-无机化学与核化学

CiteScore

3.80

自引率

10.50%

发文量

审稿时长

33 days

期刊介绍： The Journal of Fluorine Chemistry contains reviews, original papers and short communications. The journal covers all aspects of pure and applied research on the chemistry as well as on the applications of fluorine, and of compounds or materials where fluorine exercises significant effects. This can include all chemistry research areas (inorganic, organic, organometallic, macromolecular and physical chemistry) but also includes papers on biological/biochemical related aspects of Fluorine chemistry as well as medicinal, agrochemical and pharmacological research. The Journal of Fluorine Chemistry also publishes environmental and industrial papers dealing with aspects of Fluorine chemistry on energy and material sciences. Preparative and physico-chemical investigations as well as theoretical, structural and mechanistic aspects are covered. The Journal, however, does not accept work of purely routine nature. For reviews and special issues on particular topics of fluorine chemistry or from selected symposia, please contact the Regional Editors for further details.