水对锌金属-有机骨架形成动力学的影响

IF 3.4 2区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Crystal Growth & Design Pub Date : 2025-05-19 DOI:10.1021/acs.cgd.5c0004010.1021/acs.cgd.5c00040

Keenan R. Wright, Julia C. Donovan, Evelyn C. Peterson and Adam J. Matzger*,

{"title":"水对锌金属-有机骨架形成动力学的影响","authors":"Keenan R. Wright, Julia C. Donovan, Evelyn C. Peterson and Adam J. Matzger*, ","doi":"10.1021/acs.cgd.5c0004010.1021/acs.cgd.5c00040","DOIUrl":null,"url":null,"abstract":"<p >The role of water concentration, arising primarily from the metal salt and solvent, on the induction time for the solid appearance is investigated for three zinc-based metal–organic frameworks (MOFs). Precursor solutions containing higher levels of water lead to faster induction times. This is observed regardless of the particular phase formed, pointing to a common mechanism for driving supersaturation: solvent hydrolysis. The ultimate phase that arises depends on both water content and counterion employed.</p>","PeriodicalId":34,"journal":{"name":"Crystal Growth & Design","volume":"25 11","pages":"3634–3637 3634–3637"},"PeriodicalIF":3.4000,"publicationDate":"2025-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Influence of Water on Zinc Metal–Organic Framework Formation Kinetics\",\"authors\":\"Keenan R. Wright, Julia C. Donovan, Evelyn C. Peterson and Adam J. Matzger*, \",\"doi\":\"10.1021/acs.cgd.5c0004010.1021/acs.cgd.5c00040\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >The role of water concentration, arising primarily from the metal salt and solvent, on the induction time for the solid appearance is investigated for three zinc-based metal–organic frameworks (MOFs). Precursor solutions containing higher levels of water lead to faster induction times. This is observed regardless of the particular phase formed, pointing to a common mechanism for driving supersaturation: solvent hydrolysis. The ultimate phase that arises depends on both water content and counterion employed.</p>\",\"PeriodicalId\":34,\"journal\":{\"name\":\"Crystal Growth & Design\",\"volume\":\"25 11\",\"pages\":\"3634–3637 3634–3637\"},\"PeriodicalIF\":3.4000,\"publicationDate\":\"2025-05-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Crystal Growth & Design\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/acs.cgd.5c00040\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Crystal Growth & Design","FirstCategoryId":"92","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.cgd.5c00040","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

研究了主要由金属盐和溶剂引起的水浓度对三种锌基金属有机骨架（mof）的固相诱导时间的影响。前体溶液含有较高的水水平导致更快的诱导时间。无论形成的特定相如何，都可以观察到这一点，指出了驱动过饱和的共同机制：溶剂水解。产生的最终阶段取决于水的含量和所使用的反作用力。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Influence of Water on Zinc Metal–Organic Framework Formation Kinetics

查看原文本刊更多论文

Influence of Water on Zinc Metal–Organic Framework Formation Kinetics

The role of water concentration, arising primarily from the metal salt and solvent, on the induction time for the solid appearance is investigated for three zinc-based metal–organic frameworks (MOFs). Precursor solutions containing higher levels of water lead to faster induction times. This is observed regardless of the particular phase formed, pointing to a common mechanism for driving supersaturation: solvent hydrolysis. The ultimate phase that arises depends on both water content and counterion employed.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Crystal Growth & Design 化学-材料科学：综合

CiteScore

6.30

自引率

10.50%

发文量

650

审稿时长

1.9 months

期刊介绍： The aim of Crystal Growth & Design is to stimulate crossfertilization of knowledge among scientists and engineers working in the fields of crystal growth, crystal engineering, and the industrial application of crystalline materials. Crystal Growth & Design publishes theoretical and experimental studies of the physical, chemical, and biological phenomena and processes related to the design, growth, and application of crystalline materials. Synergistic approaches originating from different disciplines and technologies and integrating the fields of crystal growth, crystal engineering, intermolecular interactions, and industrial application are encouraged.