中子辐照下氯化锡的结构演变:对铟掺杂锡的研究。

IF 4.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
ACS Omega Pub Date : 2025-05-16 eCollection Date: 2025-05-27 DOI:10.1021/acsomega.5c01603
Rodrigo F B de Souza, Gabriel Silvestrin, Edson P Soares, Barbara Fasioli, de Carvalho Elita F Urano, Frederico A Genezini, Paulo S C da Silva, Almir O Neto, Delvonei A Andrade
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引用次数: 0

摘要

本研究以SnCl2为模型体系,考察了中子诱导核嬗变制备铟掺杂锡材料的可行性。中子辐照导致结构改变,包括形态改变、晶格膨胀和含铟晶相的形成。扫描电子显微镜(SEM)和电感耦合等离子体光学发射光谱(ICP-OES)证实了铟在约0.88 at的存在。%辐射后,在整个材料中均匀分布。x射线衍射(XRD)和拉曼光谱提供了结构变化的额外证据,支持铟成功融入SnCl2基体。这些结果表明,核嬗变可用于制备掺杂铟锡材料,为合成与高级应用相关的材料提供了另一种方法。该工艺利用氯的中子捕获特性来控制中子穿透,有助于开发具有特定特性的材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Structural Evolution in Tin Chloride through Neutron Irradiation: Toward Indium-Doped Tin.

Structural Evolution in Tin Chloride through Neutron Irradiation: Toward Indium-Doped Tin.

Structural Evolution in Tin Chloride through Neutron Irradiation: Toward Indium-Doped Tin.

Structural Evolution in Tin Chloride through Neutron Irradiation: Toward Indium-Doped Tin.

This study examines the feasibility of neutron-induced nuclear transmutation for producing indium-doped tin materials using SnCl2 as a model system. Neutron irradiation resulted in structural modifications, including morphological changes, lattice expansion, and the formation of indium-containing crystalline phases. Scanning Electron Microscopy (SEM) and Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) confirmed the presence of indium at approximately 0.88 at. % postirradiation, with a uniform distribution across the material. X-ray Diffraction (XRD) and Raman spectroscopy provided additional evidence of structural changes, supporting the successful incorporation of indium into the SnCl2 matrix. These results indicate that nuclear transmutation can be used to produce indium-doped tin materials, offering an alternative approach for synthesizing materials relevant to advanced applications. The process utilizes the neutron capture properties of chlorine to control neutron penetration, contributing to the development of materials with specific characteristics.

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来源期刊
ACS Omega
ACS Omega Chemical Engineering-General Chemical Engineering
CiteScore
6.60
自引率
4.90%
发文量
3945
审稿时长
2.4 months
期刊介绍: ACS Omega is an open-access global publication for scientific articles that describe new findings in chemistry and interfacing areas of science, without any perceived evaluation of immediate impact.
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