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{"title":"含不同反顺比环己二羰基氯坚韧无色聚酰胺-亚胺的合成与表征","authors":"Jinglei Xing, Lei Yang, Tianci Ma, Guofei Chen","doi":"10.1002/pi.6750","DOIUrl":null,"url":null,"abstract":"<p>With the rapid development of flexible optoelectronic devices, colorless polyimide films with excellent comprehensive performance have received widespread attention. In this work, a series of poly(amide-imide)s (PAIs) were synthesized by copolymerization of 4,4′-(hexafluoroisopropylidene)diphthalic anhydride, 1,4-cyclohexanedicarbonyl chloride (CHDC) and 2,2′-bis(trifluoromethyl)benzidine. The thermal dimensional stability and mechanical properties of the PAI films were improved due to the introduction of rigid rod-like amide bonds in the polymer chain. In addition, the PAIs with more <i>trans</i>-CHDC content showed higher glass transition temperature (<i>T</i><sub>g</sub>) and lower coefficient of thermal expansion (CTE). At the same time, the cooperative conformational transitions of cyclohexane rings in <i>trans</i>-CHDC promoted molecular chain slip and improved the film toughness. Moreover, with the introduction of the cyclohexane moiety, these PAIs had excellent optical transparency and solubility. In particular, PAI-6 exhibited high <i>T</i><sub>g</sub> of 364 °C, low CTE of 29.8 ppm K<sup>−1</sup>, high transmittance of 87% at 400 nm, tensile modulus of 3.6 GPa and elongation at break of 9.7%. Therefore, the incorporation of cyclohexane structures and amide bonds into the main chain through copolymerization with CHDC provided a simple method for the synthesis of tough colorless PAIs with excellent comprehensive properties. © 2025 Society of Chemical Industry.</p>","PeriodicalId":20404,"journal":{"name":"Polymer International","volume":"74 7","pages":"583-592"},"PeriodicalIF":2.9000,"publicationDate":"2025-02-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis and characterization of tough colorless poly(amide-imide)s containing cyclohexanedicarbonyl chloride with different trans:cis ratios\",\"authors\":\"Jinglei Xing, Lei Yang, Tianci Ma, Guofei Chen\",\"doi\":\"10.1002/pi.6750\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>With the rapid development of flexible optoelectronic devices, colorless polyimide films with excellent comprehensive performance have received widespread attention. In this work, a series of poly(amide-imide)s (PAIs) were synthesized by copolymerization of 4,4′-(hexafluoroisopropylidene)diphthalic anhydride, 1,4-cyclohexanedicarbonyl chloride (CHDC) and 2,2′-bis(trifluoromethyl)benzidine. The thermal dimensional stability and mechanical properties of the PAI films were improved due to the introduction of rigid rod-like amide bonds in the polymer chain. In addition, the PAIs with more <i>trans</i>-CHDC content showed higher glass transition temperature (<i>T</i><sub>g</sub>) and lower coefficient of thermal expansion (CTE). At the same time, the cooperative conformational transitions of cyclohexane rings in <i>trans</i>-CHDC promoted molecular chain slip and improved the film toughness. Moreover, with the introduction of the cyclohexane moiety, these PAIs had excellent optical transparency and solubility. In particular, PAI-6 exhibited high <i>T</i><sub>g</sub> of 364 °C, low CTE of 29.8 ppm K<sup>−1</sup>, high transmittance of 87% at 400 nm, tensile modulus of 3.6 GPa and elongation at break of 9.7%. Therefore, the incorporation of cyclohexane structures and amide bonds into the main chain through copolymerization with CHDC provided a simple method for the synthesis of tough colorless PAIs with excellent comprehensive properties. © 2025 Society of Chemical Industry.</p>\",\"PeriodicalId\":20404,\"journal\":{\"name\":\"Polymer International\",\"volume\":\"74 7\",\"pages\":\"583-592\"},\"PeriodicalIF\":2.9000,\"publicationDate\":\"2025-02-06\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer International\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://onlinelibrary.wiley.com/doi/10.1002/pi.6750\",\"RegionNum\":4,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"POLYMER SCIENCE\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer International","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/pi.6750","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"POLYMER SCIENCE","Score":null,"Total":0}
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