含氢碱性溶液的泄漏特性

IF 1.6 4区 工程技术 Q3 ENGINEERING, CHEMICAL
Wen Feng, Xiaojun Qiu, Xiangbin Li, Jiancheng Lin, Tie Ma, Xuefeng Lyu, Shucheng Zhang
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引用次数: 0

摘要

氢能作为21世纪的绿色清洁能源,具有燃烧性能优异、无污染、储存方式多样、发展潜力巨大等诸多优点。然而,与氢气的可燃性和爆炸性有关的安全风险不容忽视。当遇到点火源时,生产和储存过程中的氢泄漏会造成严重威胁。为了更深入地了解氢气泄漏规律,利用CFD程序模拟了典型制氢工况下含碱性液体的氢气泄漏事故,并结合射流理论进行了分析。结果表明,碱性液体对氢气泄漏的影响主要表现在稀释和促进分散。纯氢泄漏的浓度一般高于碱性液体泄漏的浓度。在相同破断速度下,碱性液体泄漏的可燃区范围在垂直方向上与纯氢泄漏的可燃区范围一致,但在水平方向上明显更大。含碱性液体的氢气泄漏在不同流速下也表现出明显不同的流型。在较高速度下,整体特征以氢气动量射流为主,呈现正浮力射流型;在较低速度下,整体特征以碱性液体为主,呈现负浮力射流型。碱性液体对氢的特征效应也随流速的变化而变化。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Leakage Characteristics of Hydrogen Gas Carrying Alkaline Solution

Hydrogen energy, as a green and clean energy source of the 21st century, boasts numerous advantages including excellent combustion performance, no pollution, diverse storage methods, and significant development potential. However, the safety risks associated with hydrogen's combustibility and explosive nature cannot be overlooked. Hydrogen leaks during production and storage pose a serious threat when encountered with an ignition source. To gain a deeper understanding of hydrogen leakage patterns, hydrogen leakage accidents involving alkaline liquid entrainment in typical scenarios of hydrogen production are simulated using the CFD program and analyzed in conjunction with jet theory. The results indicate that the impact of alkaline liquid on hydrogen leakage is primarily in dilution and promotion of dispersion. The concentration of pure hydrogen leakage is generally higher than that of leakage involving alkaline liquid. Under the same break velocity, the range of the combustible zone for leakage involving alkaline liquid is consistent with pure hydrogen leakage in the vertical direction, yet significantly larger in the horizontal direction. Hydrogen leakage involving alkaline liquid also exhibits distinctly different flow patterns at various flow rates. At higher velocities, the overall characteristics are dominated by the momentum jet of hydrogen, presenting a positive buoyant jet flow pattern, whereas at lower velocities, the scenario is dominated by the alkaline liquid, exhibiting a negative buoyant jet flow. The characteristic effects of alkaline liquid on hydrogen also vary with changes in velocity.

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来源期刊
自引率
11.10%
发文量
111
期刊介绍: Asia-Pacific Journal of Chemical Engineering is aimed at capturing current developments and initiatives in chemical engineering related and specialised areas. Publishing six issues each year, the journal showcases innovative technological developments, providing an opportunity for technology transfer and collaboration. Asia-Pacific Journal of Chemical Engineering will focus particular attention on the key areas of: Process Application (separation, polymer, catalysis, nanotechnology, electrochemistry, nuclear technology); Energy and Environmental Technology (materials for energy storage and conversion, coal gasification, gas liquefaction, air pollution control, water treatment, waste utilization and management, nuclear waste remediation); and Biochemical Engineering (including targeted drug delivery applications).
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