藕淀粉/碳纳米管复合水基润滑剂的超润滑性研究

IF 3.9 2区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY
Yusen Zhang, Wei Long*, Zhijie Zhang and Haifeng Qian, 
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引用次数: 0

摘要

润滑油广泛应用于机械、电子、医疗等领域;然而,传统的矿物油基润滑油会造成环境污染。因此,寻找可再生、无毒、环保的润滑油已成为当前的研究热点。本研究将莲藕淀粉(LRS)/碳纳米管(CNT)复合水基润滑剂引入到莲藕淀粉水基润滑剂中,并使用GCr15-SiC球盘式摩擦副进行摩擦实验。此外,通过研究摩擦对间极化电场的形成机理,探讨了复合润滑剂中藕粉颗粒和CNTs对极化电场的增强作用。最后,详细阐述了藕粉/碳纳米管复合水基润滑剂的润滑和减摩机理。结果表明:LRS2.5%/0.075%CNT润滑油在中高速工况下(分别为1200和1800 rpm)表现出优异的超润滑性能,摩擦系数低至0.004 ~ 0.005;在120 min的试验中,润滑油表现出良好的鲁棒性,在较短的磨合期(180 s)内即可进入超润滑阶段。对界面极化电场的研究表明,LRS2.5%/0.075%CNT复合润滑剂促进了相互排斥摩擦表面极化电场的形成,显著提高了摩擦副的承载能力。研究结果为开发具有显著环境效益和应用价值的绿色润滑油提供了重要参考。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Research on the Superlubricity of Lotus Root Starch/Carbon Nanotube Composite Water-Based Lubricant

Research on the Superlubricity of Lotus Root Starch/Carbon Nanotube Composite Water-Based Lubricant

Lubricants are widely used in the mechanical, electronic, and medical fields; however, traditional mineral oil-based lubricants cause environmental pollution. Therefore, the search for renewable, nontoxic, and environmentally friendly lubricants has become a current research focus. In this study, a lotus root starch (LRS)/carbon nanotube (CNT) composite water-based lubricant was introduced into a lotus root starch water-based lubricant, and frictional experiments were conducted using a GCr15-SiC ball-on-disk tribopair. Additionally, by investigating the formation mechanism of the polarization electric field between friction pairs, the enhancing effect of the lotus root starch particles and CNTs in the composite lubricant on the polarization electric field was explored. Finally, the lubrication and friction reduction mechanisms of the lotus root starch/CNT composite water-based lubricant were elaborated in detail. The results showed that the LRS2.5%/0.075%CNT lubricant exhibited excellent superlubricity under medium- and high-speed conditions (1200 and 1800 rpm, respectively), with a friction coefficient as low as 0.004–0.005. Furthermore, the lubricant showed good robustness during the 120 min experiment and could enter the superlubricity stage within a short running-in period (180 s). A study of the polarization electric field at the interface revealed that the LRS2.5%/0.075%CNT composite lubricant promoted the formation of a polarization electric field on mutually repulsive friction surfaces, significantly enhancing the load-bearing capacity of the tribopair. The findings of this study provide an important reference for the development of green lubricants with significant environmental benefits and application value.

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来源期刊
Langmuir
Langmuir 化学-材料科学:综合
CiteScore
6.50
自引率
10.30%
发文量
1464
审稿时长
2.1 months
期刊介绍: Langmuir is an interdisciplinary journal publishing articles in the following subject categories: Colloids: surfactants and self-assembly, dispersions, emulsions, foams Interfaces: adsorption, reactions, films, forces Biological Interfaces: biocolloids, biomolecular and biomimetic materials Materials: nano- and mesostructured materials, polymers, gels, liquid crystals Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do? Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*. This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).
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