Yusen Zhang, Wei Long*, Zhijie Zhang and Haifeng Qian,
{"title":"藕淀粉/碳纳米管复合水基润滑剂的超润滑性研究","authors":"Yusen Zhang, Wei Long*, Zhijie Zhang and Haifeng Qian, ","doi":"10.1021/acs.langmuir.5c0135910.1021/acs.langmuir.5c01359","DOIUrl":null,"url":null,"abstract":"<p >Lubricants are widely used in the mechanical, electronic, and medical fields; however, traditional mineral oil-based lubricants cause environmental pollution. Therefore, the search for renewable, nontoxic, and environmentally friendly lubricants has become a current research focus. In this study, a lotus root starch (LRS)/carbon nanotube (CNT) composite water-based lubricant was introduced into a lotus root starch water-based lubricant, and frictional experiments were conducted using a GCr15-SiC ball-on-disk tribopair. Additionally, by investigating the formation mechanism of the polarization electric field between friction pairs, the enhancing effect of the lotus root starch particles and CNTs in the composite lubricant on the polarization electric field was explored. Finally, the lubrication and friction reduction mechanisms of the lotus root starch/CNT composite water-based lubricant were elaborated in detail. The results showed that the LRS2.5%/0.075%CNT lubricant exhibited excellent superlubricity under medium- and high-speed conditions (1200 and 1800 rpm, respectively), with a friction coefficient as low as 0.004–0.005. Furthermore, the lubricant showed good robustness during the 120 min experiment and could enter the superlubricity stage within a short running-in period (180 s). A study of the polarization electric field at the interface revealed that the LRS2.5%/0.075%CNT composite lubricant promoted the formation of a polarization electric field on mutually repulsive friction surfaces, significantly enhancing the load-bearing capacity of the tribopair. The findings of this study provide an important reference for the development of green lubricants with significant environmental benefits and application value.</p>","PeriodicalId":50,"journal":{"name":"Langmuir","volume":"41 21","pages":"13493–13505 13493–13505"},"PeriodicalIF":3.9000,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Research on the Superlubricity of Lotus Root Starch/Carbon Nanotube Composite Water-Based Lubricant\",\"authors\":\"Yusen Zhang, Wei Long*, Zhijie Zhang and Haifeng Qian, \",\"doi\":\"10.1021/acs.langmuir.5c0135910.1021/acs.langmuir.5c01359\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Lubricants are widely used in the mechanical, electronic, and medical fields; however, traditional mineral oil-based lubricants cause environmental pollution. Therefore, the search for renewable, nontoxic, and environmentally friendly lubricants has become a current research focus. In this study, a lotus root starch (LRS)/carbon nanotube (CNT) composite water-based lubricant was introduced into a lotus root starch water-based lubricant, and frictional experiments were conducted using a GCr15-SiC ball-on-disk tribopair. Additionally, by investigating the formation mechanism of the polarization electric field between friction pairs, the enhancing effect of the lotus root starch particles and CNTs in the composite lubricant on the polarization electric field was explored. Finally, the lubrication and friction reduction mechanisms of the lotus root starch/CNT composite water-based lubricant were elaborated in detail. The results showed that the LRS2.5%/0.075%CNT lubricant exhibited excellent superlubricity under medium- and high-speed conditions (1200 and 1800 rpm, respectively), with a friction coefficient as low as 0.004–0.005. Furthermore, the lubricant showed good robustness during the 120 min experiment and could enter the superlubricity stage within a short running-in period (180 s). A study of the polarization electric field at the interface revealed that the LRS2.5%/0.075%CNT composite lubricant promoted the formation of a polarization electric field on mutually repulsive friction surfaces, significantly enhancing the load-bearing capacity of the tribopair. 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Research on the Superlubricity of Lotus Root Starch/Carbon Nanotube Composite Water-Based Lubricant
Lubricants are widely used in the mechanical, electronic, and medical fields; however, traditional mineral oil-based lubricants cause environmental pollution. Therefore, the search for renewable, nontoxic, and environmentally friendly lubricants has become a current research focus. In this study, a lotus root starch (LRS)/carbon nanotube (CNT) composite water-based lubricant was introduced into a lotus root starch water-based lubricant, and frictional experiments were conducted using a GCr15-SiC ball-on-disk tribopair. Additionally, by investigating the formation mechanism of the polarization electric field between friction pairs, the enhancing effect of the lotus root starch particles and CNTs in the composite lubricant on the polarization electric field was explored. Finally, the lubrication and friction reduction mechanisms of the lotus root starch/CNT composite water-based lubricant were elaborated in detail. The results showed that the LRS2.5%/0.075%CNT lubricant exhibited excellent superlubricity under medium- and high-speed conditions (1200 and 1800 rpm, respectively), with a friction coefficient as low as 0.004–0.005. Furthermore, the lubricant showed good robustness during the 120 min experiment and could enter the superlubricity stage within a short running-in period (180 s). A study of the polarization electric field at the interface revealed that the LRS2.5%/0.075%CNT composite lubricant promoted the formation of a polarization electric field on mutually repulsive friction surfaces, significantly enhancing the load-bearing capacity of the tribopair. The findings of this study provide an important reference for the development of green lubricants with significant environmental benefits and application value.
期刊介绍:
Langmuir is an interdisciplinary journal publishing articles in the following subject categories:
Colloids: surfactants and self-assembly, dispersions, emulsions, foams
Interfaces: adsorption, reactions, films, forces
Biological Interfaces: biocolloids, biomolecular and biomimetic materials
Materials: nano- and mesostructured materials, polymers, gels, liquid crystals
Electrochemistry: interfacial charge transfer, charge transport, electrocatalysis, electrokinetic phenomena, bioelectrochemistry
Devices and Applications: sensors, fluidics, patterning, catalysis, photonic crystals
However, when high-impact, original work is submitted that does not fit within the above categories, decisions to accept or decline such papers will be based on one criteria: What Would Irving Do?
Langmuir ranks #2 in citations out of 136 journals in the category of Physical Chemistry with 113,157 total citations. The journal received an Impact Factor of 4.384*.
This journal is also indexed in the categories of Materials Science (ranked #1) and Multidisciplinary Chemistry (ranked #5).