基于mo催化可控羰基脱氧偶联和形式脱氧N-H插入反应的2-喹啉酮和吲哚啉-3-酮的发散合成

IF 5.5 1区化学 Q2 CHEMISTRY, MULTIDISCIPLINARY

Chinese Journal of Chemistry Pub Date : 2025-04-16 DOI:10.1002/cjoc.70016

Jia-Sheng Yao, Xiaoxi Su, Yi-Zhe Yu, Jiang-Bin Wu, Shuanglin Qu, Chun-Xiang Zhuo

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引用次数: 0

摘要

报道了前所未有的mo催化可控羰基脱氧偶联和形式脱氧N-H插入反应在2-喹啉酮和吲哚啉-3-酮上的发散合成。通过简单地改变钼的催化条件，从相同的原料中生产出两类产品，收率一般都很好，化学选择性也很高。这种策略是健壮的、方便的，并且可以快速构建各种产品库。

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Divergent Synthesis of 2-Quinolinones and Indolin-3-ones via Mo-Catalyzed Controllable Carbonyl Deoxygenative Coupling and Formal Deoxygenative N—H Insertion Reactions

The divergent synthesis of 2-quinolinones and indolin-3-ones through unprecedented Mo-catalyzed controllable carbonyl deoxygenative coupling and formal deoxygenative N—H insertion reactions was reported. By simply changing the molybdenum catalytic conditions, both product categories were produced in generally good yields and with high chemoselectivities from the same starting materials. This strategy was robust, convenient and ready for the rapid construction of diverse product libraries.

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来源期刊

Chinese Journal of Chemistry 化学-化学综合

CiteScore

8.80

自引率

14.80%

发文量

422

审稿时长

1.7 months

期刊介绍： The Chinese Journal of Chemistry is an international forum for peer-reviewed original research results in all fields of chemistry. Founded in 1983 under the name Acta Chimica Sinica English Edition and renamed in 1990 as Chinese Journal of Chemistry, the journal publishes a stimulating mixture of Accounts, Full Papers, Notes and Communications in English.