新型Sm3+和Eu3+共掺杂Sr2YNbO6发红荧光粉,用于白光LED应用

IF 5.1 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS
Yuanfeng Zhang , Youzhen Shi , Chaoyong Deng , Min Zhang
{"title":"新型Sm3+和Eu3+共掺杂Sr2YNbO6发红荧光粉,用于白光LED应用","authors":"Yuanfeng Zhang ,&nbsp;Youzhen Shi ,&nbsp;Chaoyong Deng ,&nbsp;Min Zhang","doi":"10.1016/j.ceramint.2025.02.157","DOIUrl":null,"url":null,"abstract":"<div><div>A series Sm<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> and Eu<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> co-doped Sr<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>YNbO<span><math><msub><mrow></mrow><mrow><mn>6</mn></mrow></msub></math></span> phosphors were prepared by high temperature solid state reaction method in this work. The photoluminescence properties and energy transfer process were studied, and the results revealed that the photoluminescence intensity was significantly enhanced by co-doped with Eu<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span>, with the optimal concentration of 0.15mol, and the energy transfer efficiency between Sm<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> and Eu<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> ions was as high as 94.25%. In addition, the diffuse reflectance spectrum results confirmed the excitation wavelength of the sample, and the optical band gap showed concentration dependence. Finally, the lower color temperature CCT=2502K and the higher color rendering index Ra=76.4 indicate that the material has potential application value in the fields of LED and anti-counterfeiting display.</div></div>","PeriodicalId":267,"journal":{"name":"Ceramics International","volume":"51 15","pages":"Pages 19901-19909"},"PeriodicalIF":5.1000,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Novel Sm3+ and Eu3+ co-doped Sr2YNbO6 red-emitting phosphor for white LED applications\",\"authors\":\"Yuanfeng Zhang ,&nbsp;Youzhen Shi ,&nbsp;Chaoyong Deng ,&nbsp;Min Zhang\",\"doi\":\"10.1016/j.ceramint.2025.02.157\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series Sm<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> and Eu<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> co-doped Sr<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span>YNbO<span><math><msub><mrow></mrow><mrow><mn>6</mn></mrow></msub></math></span> phosphors were prepared by high temperature solid state reaction method in this work. The photoluminescence properties and energy transfer process were studied, and the results revealed that the photoluminescence intensity was significantly enhanced by co-doped with Eu<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span>, with the optimal concentration of 0.15mol, and the energy transfer efficiency between Sm<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> and Eu<span><math><msup><mrow></mrow><mrow><mn>3</mn><mo>+</mo></mrow></msup></math></span> ions was as high as 94.25%. In addition, the diffuse reflectance spectrum results confirmed the excitation wavelength of the sample, and the optical band gap showed concentration dependence. Finally, the lower color temperature CCT=2502K and the higher color rendering index Ra=76.4 indicate that the material has potential application value in the fields of LED and anti-counterfeiting display.</div></div>\",\"PeriodicalId\":267,\"journal\":{\"name\":\"Ceramics International\",\"volume\":\"51 15\",\"pages\":\"Pages 19901-19909\"},\"PeriodicalIF\":5.1000,\"publicationDate\":\"2025-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Ceramics International\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0272884225008235\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Ceramics International","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0272884225008235","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0

摘要

采用高温固相反应法制备了一系列Sm3+和Eu3+共掺杂的Sr2YNbO6荧光粉。研究了Sm3+的光致发光性能和能量传递过程,结果表明,共掺杂Eu3+显著增强了Sm3+的光致发光强度,最佳掺杂浓度为0.15mol, Sm3+与Eu3+离子之间的能量传递效率高达94.25%。此外,漫反射光谱结果证实了样品的激发波长,光学带隙呈浓度依赖性。最后,较低的色温CCT=2502K,较高的显色指数Ra=76.4,表明该材料在LED和防伪显示领域具有潜在的应用价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Novel Sm3+ and Eu3+ co-doped Sr2YNbO6 red-emitting phosphor for white LED applications
A series Sm3+ and Eu3+ co-doped Sr2YNbO6 phosphors were prepared by high temperature solid state reaction method in this work. The photoluminescence properties and energy transfer process were studied, and the results revealed that the photoluminescence intensity was significantly enhanced by co-doped with Eu3+, with the optimal concentration of 0.15mol, and the energy transfer efficiency between Sm3+ and Eu3+ ions was as high as 94.25%. In addition, the diffuse reflectance spectrum results confirmed the excitation wavelength of the sample, and the optical band gap showed concentration dependence. Finally, the lower color temperature CCT=2502K and the higher color rendering index Ra=76.4 indicate that the material has potential application value in the fields of LED and anti-counterfeiting display.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Ceramics International
Ceramics International 工程技术-材料科学:硅酸盐
CiteScore
9.40
自引率
15.40%
发文量
4558
审稿时长
25 days
期刊介绍: Ceramics International covers the science of advanced ceramic materials. The journal encourages contributions that demonstrate how an understanding of the basic chemical and physical phenomena may direct materials design and stimulate ideas for new or improved processing techniques, in order to obtain materials with desired structural features and properties. Ceramics International covers oxide and non-oxide ceramics, functional glasses, glass ceramics, amorphous inorganic non-metallic materials (and their combinations with metal and organic materials), in the form of particulates, dense or porous bodies, thin/thick films and laminated, graded and composite structures. Process related topics such as ceramic-ceramic joints or joining ceramics with dissimilar materials, as well as surface finishing and conditioning are also covered. Besides traditional processing techniques, manufacturing routes of interest include innovative procedures benefiting from externally applied stresses, electromagnetic fields and energetic beams, as well as top-down and self-assembly nanotechnology approaches. In addition, the journal welcomes submissions on bio-inspired and bio-enabled materials designs, experimentally validated multi scale modelling and simulation for materials design, and the use of the most advanced chemical and physical characterization techniques of structure, properties and behaviour. Technologically relevant low-dimensional systems are a particular focus of Ceramics International. These include 0, 1 and 2-D nanomaterials (also covering CNTs, graphene and related materials, and diamond-like carbons), their nanocomposites, as well as nano-hybrids and hierarchical multifunctional nanostructures that might integrate molecular, biological and electronic components.
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信