{"title":"双特性发射的Dy1-xTbx-datrz MOF荧光强度比温度传感","authors":"Zitao Yan , Chuanfang Wu , Yong Pu , Dachuan Zhu","doi":"10.1016/j.physb.2025.417457","DOIUrl":null,"url":null,"abstract":"<div><div>A series of dual-lanthanide metal-organic frameworks (Dy<sub>1-x</sub>Tb<sub>x</sub>-datrz MOFs) have been synthesized successfully via solvothermal method using DMF solution and confirmed by XRD and FT-IR patterns, which were further revealed as the structure composed of regular block crystals by SEM observation. Subsequently, the solid-state luminescence spectra of all the Dy<sub>1-x</sub>Tb<sub>x</sub>-datrz MOFs showed the dual characteristic emission peaks of Dy<sup>3+</sup> and Tb<sup>3+</sup> under the excitation at 350 nm. Meanwhile, a concentration quenching effect was found like monometallic luminescence MOF, among which Dy<sub>0.5</sub>Tb<sub>0.5</sub>-datrz exhibited the strongest emission intensity. Notably, the ratio-metric fluorescence temperature sensing performance and thermal cycle stability of Dy<sub>0.5</sub>Tb<sub>0.5</sub>-datrz were investigated, of which the sensitivity value (Sr) ranged from 0.2737 %K<sup>−1</sup> to 0.4421 %K<sup>−1</sup> and δT value varied between 0.0300K and 0.0485K during 293K–473K, combined with a good thermal cycle stability. Therefore, Dy<sub>0.5</sub>Tb<sub>0.5</sub>-datrz with dual characteristic emission has the potential for ratio-metric fluorescence temperature sensing.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":"714 ","pages":"Article 417457"},"PeriodicalIF":2.8000,"publicationDate":"2025-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Fluorescence intensity ratio temperature sensing of Dy1-xTbx-datrz MOF with dual characteristic emission\",\"authors\":\"Zitao Yan , Chuanfang Wu , Yong Pu , Dachuan Zhu\",\"doi\":\"10.1016/j.physb.2025.417457\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A series of dual-lanthanide metal-organic frameworks (Dy<sub>1-x</sub>Tb<sub>x</sub>-datrz MOFs) have been synthesized successfully via solvothermal method using DMF solution and confirmed by XRD and FT-IR patterns, which were further revealed as the structure composed of regular block crystals by SEM observation. Subsequently, the solid-state luminescence spectra of all the Dy<sub>1-x</sub>Tb<sub>x</sub>-datrz MOFs showed the dual characteristic emission peaks of Dy<sup>3+</sup> and Tb<sup>3+</sup> under the excitation at 350 nm. Meanwhile, a concentration quenching effect was found like monometallic luminescence MOF, among which Dy<sub>0.5</sub>Tb<sub>0.5</sub>-datrz exhibited the strongest emission intensity. Notably, the ratio-metric fluorescence temperature sensing performance and thermal cycle stability of Dy<sub>0.5</sub>Tb<sub>0.5</sub>-datrz were investigated, of which the sensitivity value (Sr) ranged from 0.2737 %K<sup>−1</sup> to 0.4421 %K<sup>−1</sup> and δT value varied between 0.0300K and 0.0485K during 293K–473K, combined with a good thermal cycle stability. Therefore, Dy<sub>0.5</sub>Tb<sub>0.5</sub>-datrz with dual characteristic emission has the potential for ratio-metric fluorescence temperature sensing.</div></div>\",\"PeriodicalId\":20116,\"journal\":{\"name\":\"Physica B-condensed Matter\",\"volume\":\"714 \",\"pages\":\"Article 417457\"},\"PeriodicalIF\":2.8000,\"publicationDate\":\"2025-05-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Physica B-condensed Matter\",\"FirstCategoryId\":\"101\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0921452625005745\",\"RegionNum\":3,\"RegionCategory\":\"物理与天体物理\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"PHYSICS, CONDENSED MATTER\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Physica B-condensed Matter","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0921452625005745","RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"PHYSICS, CONDENSED MATTER","Score":null,"Total":0}
Fluorescence intensity ratio temperature sensing of Dy1-xTbx-datrz MOF with dual characteristic emission
A series of dual-lanthanide metal-organic frameworks (Dy1-xTbx-datrz MOFs) have been synthesized successfully via solvothermal method using DMF solution and confirmed by XRD and FT-IR patterns, which were further revealed as the structure composed of regular block crystals by SEM observation. Subsequently, the solid-state luminescence spectra of all the Dy1-xTbx-datrz MOFs showed the dual characteristic emission peaks of Dy3+ and Tb3+ under the excitation at 350 nm. Meanwhile, a concentration quenching effect was found like monometallic luminescence MOF, among which Dy0.5Tb0.5-datrz exhibited the strongest emission intensity. Notably, the ratio-metric fluorescence temperature sensing performance and thermal cycle stability of Dy0.5Tb0.5-datrz were investigated, of which the sensitivity value (Sr) ranged from 0.2737 %K−1 to 0.4421 %K−1 and δT value varied between 0.0300K and 0.0485K during 293K–473K, combined with a good thermal cycle stability. Therefore, Dy0.5Tb0.5-datrz with dual characteristic emission has the potential for ratio-metric fluorescence temperature sensing.
期刊介绍:
Physica B: Condensed Matter comprises all condensed matter and material physics that involve theoretical, computational and experimental work.
Papers should contain further developments and a proper discussion on the physics of experimental or theoretical results in one of the following areas:
-Magnetism
-Materials physics
-Nanostructures and nanomaterials
-Optics and optical materials
-Quantum materials
-Semiconductors
-Strongly correlated systems
-Superconductivity
-Surfaces and interfaces