Koki Nozawa , Seo Jisol , Takamitsu Ishiyama , Noriyuki Saitoh , Noriko Yoshizawa , Takashi Suemasu , Kaoru Toko
{"title":"直接在绝缘体上形成的多晶In1−xGaxAs薄膜的晶体和电学性质","authors":"Koki Nozawa , Seo Jisol , Takamitsu Ishiyama , Noriyuki Saitoh , Noriko Yoshizawa , Takashi Suemasu , Kaoru Toko","doi":"10.1016/j.materresbull.2025.113581","DOIUrl":null,"url":null,"abstract":"<div><div>Polycrystalline In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As thin films are promising for high-performance electronics on versatile substrates, including transistors, solar cells, optical communication devices, and infrared sensors. This study examines the effects of composition, deposition temperature, and impurity doping on the grain size, crystal orientation, nanostructure, and electrical properties of In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As layers, utilizing various evaluation methods with machine learning. The results demonstrate that the composition and deposition temperature significantly influence the crystallinity and crystal orientations. Higher In compositions and deposition temperatures yield In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As with enhanced crystallinity. The undoped samples exhibit n-type conduction, which is likely attributable to antisite defects. Increasing the In content and deposition temperature increases the electron concentration and mobility up to 3 × 10<sup>18</sup> cm<sup>−3</sup> and 310 cm<sup>2</sup> V<sup>−1</sup>s<sup>−1</sup>, respectively. Sn is an effective n-type dopant, facilitating the control of electron concentration within the range of 10<sup>17</sup>–10<sup>19</sup> cm<sup>−3</sup>. These findings offer valuable insights into the application of In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As in high-performance electronic devices.</div></div>","PeriodicalId":18265,"journal":{"name":"Materials Research Bulletin","volume":"191 ","pages":"Article 113581"},"PeriodicalIF":5.7000,"publicationDate":"2025-05-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Crystal and electrical properties of polycrystalline In1−xGaxAs thin films directly formed on insulators\",\"authors\":\"Koki Nozawa , Seo Jisol , Takamitsu Ishiyama , Noriyuki Saitoh , Noriko Yoshizawa , Takashi Suemasu , Kaoru Toko\",\"doi\":\"10.1016/j.materresbull.2025.113581\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>Polycrystalline In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As thin films are promising for high-performance electronics on versatile substrates, including transistors, solar cells, optical communication devices, and infrared sensors. This study examines the effects of composition, deposition temperature, and impurity doping on the grain size, crystal orientation, nanostructure, and electrical properties of In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As layers, utilizing various evaluation methods with machine learning. The results demonstrate that the composition and deposition temperature significantly influence the crystallinity and crystal orientations. Higher In compositions and deposition temperatures yield In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As with enhanced crystallinity. The undoped samples exhibit n-type conduction, which is likely attributable to antisite defects. Increasing the In content and deposition temperature increases the electron concentration and mobility up to 3 × 10<sup>18</sup> cm<sup>−3</sup> and 310 cm<sup>2</sup> V<sup>−1</sup>s<sup>−1</sup>, respectively. Sn is an effective n-type dopant, facilitating the control of electron concentration within the range of 10<sup>17</sup>–10<sup>19</sup> cm<sup>−3</sup>. These findings offer valuable insights into the application of In<sub>1−</sub><em><sub>x</sub></em>Ga<em><sub>x</sub></em>As in high-performance electronic devices.</div></div>\",\"PeriodicalId\":18265,\"journal\":{\"name\":\"Materials Research Bulletin\",\"volume\":\"191 \",\"pages\":\"Article 113581\"},\"PeriodicalIF\":5.7000,\"publicationDate\":\"2025-05-26\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Research Bulletin\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0025540825002892\",\"RegionNum\":3,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Research Bulletin","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0025540825002892","RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
Crystal and electrical properties of polycrystalline In1−xGaxAs thin films directly formed on insulators
Polycrystalline In1−xGaxAs thin films are promising for high-performance electronics on versatile substrates, including transistors, solar cells, optical communication devices, and infrared sensors. This study examines the effects of composition, deposition temperature, and impurity doping on the grain size, crystal orientation, nanostructure, and electrical properties of In1−xGaxAs layers, utilizing various evaluation methods with machine learning. The results demonstrate that the composition and deposition temperature significantly influence the crystallinity and crystal orientations. Higher In compositions and deposition temperatures yield In1−xGaxAs with enhanced crystallinity. The undoped samples exhibit n-type conduction, which is likely attributable to antisite defects. Increasing the In content and deposition temperature increases the electron concentration and mobility up to 3 × 1018 cm−3 and 310 cm2 V−1s−1, respectively. Sn is an effective n-type dopant, facilitating the control of electron concentration within the range of 1017–1019 cm−3. These findings offer valuable insights into the application of In1−xGaxAs in high-performance electronic devices.
期刊介绍:
Materials Research Bulletin is an international journal reporting high-impact research on processing-structure-property relationships in functional materials and nanomaterials with interesting electronic, magnetic, optical, thermal, mechanical or catalytic properties. Papers purely on thermodynamics or theoretical calculations (e.g., density functional theory) do not fall within the scope of the journal unless they also demonstrate a clear link to physical properties. Topics covered include functional materials (e.g., dielectrics, pyroelectrics, piezoelectrics, ferroelectrics, relaxors, thermoelectrics, etc.); electrochemistry and solid-state ionics (e.g., photovoltaics, batteries, sensors, and fuel cells); nanomaterials, graphene, and nanocomposites; luminescence and photocatalysis; crystal-structure and defect-structure analysis; novel electronics; non-crystalline solids; flexible electronics; protein-material interactions; and polymeric ion-exchange membranes.