CO2电解中的甲醛缩合途径

IF 42.8 1区化学 Q1 CHEMISTRY, PHYSICAL

Nature Catalysis Pub Date : 2025-05-28 DOI:10.1038/s41929-025-01344-3

Huali Wu, Damien Voiry

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引用次数: 0

摘要

在二氧化碳（CO2）电还原界有一个广泛的共识，即C - C键偶联步骤通常涉及*C(H)O中间体在催化剂表面的二聚化。现在报道了另一种途径，其中甲醛介导的缩合机制启动C-C键的形成，从而促进CO2电转化为C3+液体产物。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

A formaldehyde condensation pathway in CO2 electrolysis

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A formaldehyde condensation pathway in CO2 electrolysis

There is a broad consensus in the carbon dioxide (CO2) electroreduction community that the C–C bond coupling step typically involves the dimerization of *C(H)O intermediates on the catalyst surface. An alternative pathway is now reported, in which a formaldehyde-mediated condensation mechanism initiates C–C bond formation, thereby promoting the electro-conversion of CO2 to C3+ liquid products.

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来源期刊

Nature Catalysis Chemical Engineering-Bioengineering

CiteScore

52.10

自引率

1.10%

发文量

140

期刊介绍： Nature Catalysis serves as a platform for researchers across chemistry and related fields, focusing on homogeneous catalysis, heterogeneous catalysis, and biocatalysts, encompassing both fundamental and applied studies. With a particular emphasis on advancing sustainable industries and processes, the journal provides comprehensive coverage of catalysis research, appealing to scientists, engineers, and researchers in academia and industry. Maintaining the high standards of the Nature brand, Nature Catalysis boasts a dedicated team of professional editors, rigorous peer-review processes, and swift publication times, ensuring editorial independence and quality. The journal publishes work spanning heterogeneous catalysis, homogeneous catalysis, and biocatalysis, covering areas such as catalytic synthesis, mechanisms, characterization, computational studies, nanoparticle catalysis, electrocatalysis, photocatalysis, environmental catalysis, asymmetric catalysis, and various forms of organocatalysis.