手性环丙烷与密闭空间中的光

IF 42.8 1区化学 Q1 CHEMISTRY, PHYSICAL

Nature Catalysis Pub Date : 2025-05-28 DOI:10.1038/s41929-025-01345-2

Magdalena Walewska-Królikiewicz, Dorota Gryko

引用次数: 0

摘要

从非手性构建块对映选择性合成小环烷烃的几种策略是已知的，但一般和可持续的方法仍然是一个艰巨的挑战。目前，不对称反离子定向催化与光氧化还原活化的合作是金属有机和酶法合成手性环丙烷的补充。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Chiral cyclopropanes with light in confined space

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Chiral cyclopropanes with light in confined space

Several strategies for the enantioselective synthesis of small cyclic alkanes from achiral building blocks are known, but general and sustainable methods still represent a daunting challenge. Now, the cooperation of asymmetric counterion-directed catalysis with photoredox activation complements metalloorganic and enzymatic methods for the synthesis of chiral cyclopropanes.

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来源期刊

Nature Catalysis Chemical Engineering-Bioengineering

CiteScore

52.10

自引率

1.10%

发文量

140

期刊介绍： Nature Catalysis serves as a platform for researchers across chemistry and related fields, focusing on homogeneous catalysis, heterogeneous catalysis, and biocatalysts, encompassing both fundamental and applied studies. With a particular emphasis on advancing sustainable industries and processes, the journal provides comprehensive coverage of catalysis research, appealing to scientists, engineers, and researchers in academia and industry. Maintaining the high standards of the Nature brand, Nature Catalysis boasts a dedicated team of professional editors, rigorous peer-review processes, and swift publication times, ensuring editorial independence and quality. The journal publishes work spanning heterogeneous catalysis, homogeneous catalysis, and biocatalysis, covering areas such as catalytic synthesis, mechanisms, characterization, computational studies, nanoparticle catalysis, electrocatalysis, photocatalysis, environmental catalysis, asymmetric catalysis, and various forms of organocatalysis.