Preparation of Few-Micron-Thick Free-Standing Au-Nanorod/UDMA-TEGDMA Nanocomposite Films by Using PVA Sacrificial Layers.

A method to prepare free-standing, few-micron-thick films from a dental photopolymer resin, namely UDMA-TEGDMA in a 3:1 weight ratio, doped with gold nanorods, is presented. The method is based on a sandwich structure consisting of a 4 μm thick PVA sacrificial layer, the Au-nanorod/UDMA-TEGDMA nanocomposite layer, and glycerol, all spin-coated sequentially onto a glass slide. Glycerol serves as a cover layer to shut out oxygen during photopolymerization, while the water-soluble PVA enables the subsequent detachment of the nanocomposite film by simple immersion into a liquid bath. Layer thicknesses were controlled by profilometry, while the presence of homogeneously dispersed gold nanorods was confirmed by optical spectroscopy and dark-field optical microscopy. A total of five similar spin-coating scenarios were tested, out of which two approaches produced positive results, with final nanocomposite layer thicknesses in the 2.5-4 μm range, which is smaller than the usual thickness of the oxygen inhibition layer (OIL) commonly present in these types of resins. Optimization of these technological processes and parameters to control film thickness and consistency is discussed in detail.