Advancing Nanogenerators: The Role of 3D-Printed Nanocomposites in Energy Harvesting.

Nanogenerators have garnered significant scholarly interest as a groundbreaking approach to energy harvesting, encompassing applications in self-sustaining electronics, biomedical devices, and environmental monitoring. The rise of additive manufacturing has fundamentally transformed the production processes of nanocomposites, allowing for the detailed design and refinement of materials aimed at optimizing energy generation. This review presents a comprehensive analysis of 3D-printed nanocomposites in the context of nanogenerator applications. By employing layer-by-layer deposition, multi-material integration, and custom microstructural architectures, 3D-printed nanocomposites exhibit improved mechanical properties, superior energy conversion efficiency, and increased structural complexity when compared to their conventionally manufactured counterparts. Polymers, particularly those with inherent dielectric, piezoelectric, or triboelectric characteristics, serve as critical functional matrices in these composites, offering mechanical flexibility, processability, and compatibility with diverse nanoparticles. In particular, the careful regulation of the nanoparticle distribution in 3D printing significantly enhances piezoelectric and triboelectric functionalities, resulting in a higher energy output and greater consistency. Recent investigations into three-dimensional-printed nanogenerators reveal extraordinary outputs, encompassing peak voltages of as much as 120 V for BaTiO₃-PVDF composites, energy densities surpassing 3.5 mJ/cm², and effective d₃₃ values attaining 35 pC/N, thereby emphasizing the transformative influence of additive manufacturing on the performance of energy harvesting. Furthermore, the scalability and cost-effectiveness inherent in additive manufacturing provide substantial benefits by reducing material waste and streamlining multi-phase processing. Nonetheless, despite these advantages, challenges such as environmental resilience, long-term durability, and the fine-tuning of printing parameters remain critical hurdles for widespread adoption. This assessment highlights the transformative potential of 3D printing in advancing nanogenerator technology and offers valuable insights into future research directions for developing high-efficiency, sustainable, and scalable energy-harvesting systems.