应力-应力相关性中的尖点奇点揭示了胶体凝胶的刚性。

IF 2.9 3区 化学 Q3 CHEMISTRY, PHYSICAL
Soft Matter Pub Date : 2025-05-27 DOI:10.1039/d5sm00296f
Albert Countryman, H A Vinutha, Fabiola Diaz Ruiz, Xiaoming Mao, Emanuela Del Gado, Bulbul Chakraborty
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引用次数: 0

摘要

我们证明,在计算机模拟中获得的二维模型胶体凝胶中微观应力的空间相关性可以通过预应力固体涌现弹性理论(矢量电荷理论)的预测来定量描述。通过将刚性分析与应力相关性提供的特征相结合,我们表明理论预测能够区分刚性和软性凝胶,并根据在大长度尺度上出现的捏点奇点的大小来量化这种区分,在理论上,这直接来源于内力上的机械平衡所施加的约束。我们还使用理论预测来研究应力传递和刚度之间的耦合,并且我们探索了一种类似debye的筛选机制的可能性,该机制将修改理论预测低于特征长度尺度。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Pinch-point singularities in stress-stress correlations reveal rigidity in colloidal gels.

We demonstrate that the spatial correlations of microscopic stresses in 2D model colloidal gels obtained in computer simulations can be quantitatively described by the predictions of a theory for emergent elasticity of pre-stressed solids (vector charge theory). By combining a rigidity analysis with the characterization provided by the stress correlations, we show that the theoretical predictions are able to distinguish rigid from floppy gels, and quantify that distinction in terms of the size of a pinch-point singularity emerging at large length scales, which, in the theory, directly derives from the constraints imposed by mechanical equilibrium on the internal forces. We also use the theoretical predictions to investigate the coupling between stress-transmission and rigidity, and we explore the possibility of a Debye-like screening mechanism that would modify the theory predictions below a characteristic length scale.

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来源期刊
Soft Matter
Soft Matter 工程技术-材料科学:综合
CiteScore
6.00
自引率
5.90%
发文量
891
审稿时长
1.9 months
期刊介绍: Soft Matter is an international journal published by the Royal Society of Chemistry using Engineering-Materials Science: A Synthesis as its research focus. It publishes original research articles, review articles, and synthesis articles related to this field, reporting the latest discoveries in the relevant theoretical, practical, and applied disciplines in a timely manner, and aims to promote the rapid exchange of scientific information in this subject area. The journal is an open access journal. The journal is an open access journal and has not been placed on the alert list in the last three years.
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