异芳酮三环骨架的合成。

IF 2.9 3区化学 Q1 CHEMISTRY, ORGANIC

Organic & Biomolecular Chemistry Pub Date : 2025-05-28 DOI:10.1039/d5ob00644a

Guoqing Sui, Xiaoqing Song, Huihui Guo, Xiaolan Xie, Li Ren, Wenming Zhou, Hong-Dong Hao

引用次数: 0

摘要

报道了一种合成二萜异芳酮的6-5-5三环骨架的方法。该合成策略采用分子间Diels-Alder反应构建顺式氢丹部分，并采用交叉偶联-异构化-分子内alder -烯环化级联有效组装异常芳酮的6-5-5三环骨架。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Synthesis of the tricyclic skeleton of aberrarone.

A synthesis of the 6-5-5 tricyclic skeleton of the diterpenoid aberrarone is reported. The synthesis strategically features an intermolecular Diels-Alder reaction to construct the cis-hydrindane moiety and a cross-coupling-isomerization-intramolecular Alder-ene cyclization cascade to efficiently assemble the 6-5-5 tricyclic skeleton of aberrarone.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Organic & Biomolecular Chemistry 化学-有机化学

CiteScore

5.50

自引率

9.40%

发文量

1056

审稿时长

1.3 months

期刊介绍： Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.