基于InAs纳米线的双电传感器,可同时进行气体检测。

IF 5.5 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY
ACS Applied Nano Materials Pub Date : 2025-05-08 eCollection Date: 2025-05-23 DOI:10.1021/acsanm.4c07238
Camilla Baratto, Egit Musaev, Valeria Demontis, Stefano Luin, Valentina Zannier, Lucia Sorba, Guido Faglia, Luigi Rovati, Francesco Rossella
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引用次数: 0

摘要

外延生长的InAs NWs由于在NW表面的费米能级钉住而与电传感应用相关,并且对周围环境高度敏感。虽然单个NW生长批次由数百万个几乎相同的NW副本组成,但实际样品在NW大小、形状和结构上显示出细微的差异,这可能会影响检测性能。在这里,电气体检测被研究在两个名义上相同的或双器件制造从相同的NW生长批次开始。将两个独立的纤锌矿InAs NWs以2 μm的距离以90°的相对方向放置在制造基板上,每个NW都电接触,并将纳米器件暴露在湿度和合成空气中稀释的NO2通量中。在暴露于不同气体和浓度时,同时测量每个纳米器件中的电信号与时间的关系。观察到的检测限为2 ppm的NO2和20%的相对湿度。通过计算实验信号对的自相关和互相关函数,利用相关分析方法,表明两个纳米器件的信号噪声缺乏互相关,这表明双胞胎之间的信号差异主要归因于制造方案的不理想和两种纳米结构的纳米级差异,而不是不同的环境条件。虽然InAs纳米线在这里被用作同时气体传感的演示,但该方法是通用的,实际上适用于任何适合实现双端电子器件的纳米级材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
InAs Nanowire-Based Twin Electrical Sensors Enabling Simultaneous Gas Detection.

Epitaxially grown InAs NWs are relevant for electrical sensing applications due to the Fermi level pinning at the NW surface and are highly sensitive to the surrounding environment. While a single NW growth batch consists of millions of virtually identical replicas of the same NW, real samples display subtle differences in NW size, shape, and structure, which may affect detection performance. Here, electrical gas detection is investigated in two nominally identical or twin devices fabricated starting from the same NW growth batch. Two individual wurtzite InAs NWs are placed onto a fabrication substrate at a 2 μm distance with a 90° relative orientation, each NW is electrically contacted, and the nanodevices are exposed to humidity and NO2 flux diluted in synthetic air. Electrical signal versus time is measured simultaneously in each nanodevice upon exposure to different gases and concentrations. The observed detection limit is 2 ppm for NO2 and 20% for relative humidity. Correlation analysis methods are exploited by calculating autocorrelation and cross-correlation functions for the experimental signal pairs, indicating lack of cross-correlation in the signal noise of the two nanodevices, suggesting that signal differences between the twins could be ascribed mainly to nonidealities in the fabrication protocol and nanoscopic differences in the two nanostructures, rather than to different environmental conditions. While InAs nanowires are used here as demonstrators of simultaneous gas sensing, the approach is general and virtually applies to any nanoscale material suitable for the realization of two-terminal electronic devices.

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来源期刊
CiteScore
8.30
自引率
3.40%
发文量
1601
期刊介绍: ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.
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