Camilla Baratto, Egit Musaev, Valeria Demontis, Stefano Luin, Valentina Zannier, Lucia Sorba, Guido Faglia, Luigi Rovati, Francesco Rossella
{"title":"基于InAs纳米线的双电传感器,可同时进行气体检测。","authors":"Camilla Baratto, Egit Musaev, Valeria Demontis, Stefano Luin, Valentina Zannier, Lucia Sorba, Guido Faglia, Luigi Rovati, Francesco Rossella","doi":"10.1021/acsanm.4c07238","DOIUrl":null,"url":null,"abstract":"<p><p>Epitaxially grown InAs NWs are relevant for electrical sensing applications due to the Fermi level pinning at the NW surface and are highly sensitive to the surrounding environment. While a single NW growth batch consists of millions of virtually identical replicas of the same NW, real samples display subtle differences in NW size, shape, and structure, which may affect detection performance. Here, electrical gas detection is investigated in two nominally identical or twin devices fabricated starting from the same NW growth batch. Two individual wurtzite InAs NWs are placed onto a fabrication substrate at a 2 μm distance with a 90° relative orientation, each NW is electrically contacted, and the nanodevices are exposed to humidity and NO<sub>2</sub> flux diluted in synthetic air. Electrical signal versus time is measured simultaneously in each nanodevice upon exposure to different gases and concentrations. The observed detection limit is 2 ppm for NO<sub>2</sub> and 20% for relative humidity. Correlation analysis methods are exploited by calculating autocorrelation and cross-correlation functions for the experimental signal pairs, indicating lack of cross-correlation in the signal noise of the two nanodevices, suggesting that signal differences between the twins could be ascribed mainly to nonidealities in the fabrication protocol and nanoscopic differences in the two nanostructures, rather than to different environmental conditions. While InAs nanowires are used here as demonstrators of simultaneous gas sensing, the approach is general and virtually applies to any nanoscale material suitable for the realization of two-terminal electronic devices.</p>","PeriodicalId":6,"journal":{"name":"ACS Applied Nano Materials","volume":"8 20","pages":"10275-10286"},"PeriodicalIF":5.5000,"publicationDate":"2025-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12107530/pdf/","citationCount":"0","resultStr":"{\"title\":\"InAs Nanowire-Based Twin Electrical Sensors Enabling Simultaneous Gas Detection.\",\"authors\":\"Camilla Baratto, Egit Musaev, Valeria Demontis, Stefano Luin, Valentina Zannier, Lucia Sorba, Guido Faglia, Luigi Rovati, Francesco Rossella\",\"doi\":\"10.1021/acsanm.4c07238\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Epitaxially grown InAs NWs are relevant for electrical sensing applications due to the Fermi level pinning at the NW surface and are highly sensitive to the surrounding environment. While a single NW growth batch consists of millions of virtually identical replicas of the same NW, real samples display subtle differences in NW size, shape, and structure, which may affect detection performance. Here, electrical gas detection is investigated in two nominally identical or twin devices fabricated starting from the same NW growth batch. Two individual wurtzite InAs NWs are placed onto a fabrication substrate at a 2 μm distance with a 90° relative orientation, each NW is electrically contacted, and the nanodevices are exposed to humidity and NO<sub>2</sub> flux diluted in synthetic air. Electrical signal versus time is measured simultaneously in each nanodevice upon exposure to different gases and concentrations. The observed detection limit is 2 ppm for NO<sub>2</sub> and 20% for relative humidity. Correlation analysis methods are exploited by calculating autocorrelation and cross-correlation functions for the experimental signal pairs, indicating lack of cross-correlation in the signal noise of the two nanodevices, suggesting that signal differences between the twins could be ascribed mainly to nonidealities in the fabrication protocol and nanoscopic differences in the two nanostructures, rather than to different environmental conditions. While InAs nanowires are used here as demonstrators of simultaneous gas sensing, the approach is general and virtually applies to any nanoscale material suitable for the realization of two-terminal electronic devices.</p>\",\"PeriodicalId\":6,\"journal\":{\"name\":\"ACS Applied Nano Materials\",\"volume\":\"8 20\",\"pages\":\"10275-10286\"},\"PeriodicalIF\":5.5000,\"publicationDate\":\"2025-05-08\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12107530/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ACS Applied Nano Materials\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://doi.org/10.1021/acsanm.4c07238\",\"RegionNum\":2,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/5/23 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ACS Applied Nano Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1021/acsanm.4c07238","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/5/23 0:00:00","PubModel":"eCollection","JCR":"Q2","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
InAs Nanowire-Based Twin Electrical Sensors Enabling Simultaneous Gas Detection.
Epitaxially grown InAs NWs are relevant for electrical sensing applications due to the Fermi level pinning at the NW surface and are highly sensitive to the surrounding environment. While a single NW growth batch consists of millions of virtually identical replicas of the same NW, real samples display subtle differences in NW size, shape, and structure, which may affect detection performance. Here, electrical gas detection is investigated in two nominally identical or twin devices fabricated starting from the same NW growth batch. Two individual wurtzite InAs NWs are placed onto a fabrication substrate at a 2 μm distance with a 90° relative orientation, each NW is electrically contacted, and the nanodevices are exposed to humidity and NO2 flux diluted in synthetic air. Electrical signal versus time is measured simultaneously in each nanodevice upon exposure to different gases and concentrations. The observed detection limit is 2 ppm for NO2 and 20% for relative humidity. Correlation analysis methods are exploited by calculating autocorrelation and cross-correlation functions for the experimental signal pairs, indicating lack of cross-correlation in the signal noise of the two nanodevices, suggesting that signal differences between the twins could be ascribed mainly to nonidealities in the fabrication protocol and nanoscopic differences in the two nanostructures, rather than to different environmental conditions. While InAs nanowires are used here as demonstrators of simultaneous gas sensing, the approach is general and virtually applies to any nanoscale material suitable for the realization of two-terminal electronic devices.
期刊介绍:
ACS Applied Nano Materials is an interdisciplinary journal publishing original research covering all aspects of engineering, chemistry, physics and biology relevant to applications of nanomaterials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important applications of nanomaterials.