锑与铋：Cat{[MCl5](I2)}卤素键联超分子配合物的结构差异

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-05-27 DOI:10.1039/d5dt00697j

Nikita A. Korobeynikov, Andrey N. Usoltsev, Maksim Nailyevich Sokolov, Alexander S. Novikov, Sergey A Adonin

{"title":"锑与铋：Cat{[MCl5](I2)}卤素键联超分子配合物的结构差异","authors":"Nikita A. Korobeynikov, Andrey N. Usoltsev, Maksim Nailyevich Sokolov, Alexander S. Novikov, Sergey A Adonin","doi":"10.1039/d5dt00697j","DOIUrl":null,"url":null,"abstract":"Four new hybrid chloroantimonates(III) and chrorobismuthates(III) with halogen bond-linked I2, (H2bpe){[MCl5](I2)} (M = Sb(III) (1); M = Bi(III) (2); bpe – 1,2-bis(4-pyridil)ethane) and (H2bpp){[MCl5](I2)} – (M = Sb(III) (3); M = Bi(III) (4); bpp = 1,3-bis(4-pyridil)propane)) were synthesized via reaction between Sb2O3/Bi2O3, I2 and corresponding bis(pyridines) in HCl. Despite sharing the same formulae of supramolecular anionic parts, they show significant structural diversity, revealing three different structural types. Features of halogen bond in 1-4 were examined by theoretical methods.","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":"14 1","pages":""},"PeriodicalIF":3.5000,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Antimony vs bismuth: structural differences in Cat{[MCl5](I2)} halogen bond-linked supramolecular complexes\",\"authors\":\"Nikita A. Korobeynikov, Andrey N. Usoltsev, Maksim Nailyevich Sokolov, Alexander S. Novikov, Sergey A Adonin\",\"doi\":\"10.1039/d5dt00697j\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Four new hybrid chloroantimonates(III) and chrorobismuthates(III) with halogen bond-linked I2, (H2bpe){[MCl5](I2)} (M = Sb(III) (1); M = Bi(III) (2); bpe – 1,2-bis(4-pyridil)ethane) and (H2bpp){[MCl5](I2)} – (M = Sb(III) (3); M = Bi(III) (4); bpp = 1,3-bis(4-pyridil)propane)) were synthesized via reaction between Sb2O3/Bi2O3, I2 and corresponding bis(pyridines) in HCl. Despite sharing the same formulae of supramolecular anionic parts, they show significant structural diversity, revealing three different structural types. Features of halogen bond in 1-4 were examined by theoretical methods.\",\"PeriodicalId\":71,\"journal\":{\"name\":\"Dalton Transactions\",\"volume\":\"14 1\",\"pages\":\"\"},\"PeriodicalIF\":3.5000,\"publicationDate\":\"2025-05-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Dalton Transactions\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1039/d5dt00697j\",\"RegionNum\":3,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, INORGANIC & NUCLEAR\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1039/d5dt00697j","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}

引用次数: 0

摘要

四种新的卤素键连接的氯锑酸盐（III）和绿铋酸盐（III），（H2bpe）{[MCl5](I2)} (M = Sb(III) (1)；M = Bi(III) (2)；bpe - 1,以叔(4-pyridil)乙烷)和(H2bpp) {[MCl5] (I2)} (M =某人(III) (3);M = Bi(III) (4)；bpp = 1,3-双（4-吡啶）丙烷)是由Sb2O3/Bi2O3、I2和相应的双（吡啶）在HCl中反应合成的。尽管它们的超分子阴离子部分的分子式相同，但它们表现出显著的结构多样性，揭示出三种不同的结构类型。用理论方法研究了1-4中卤素键的特征。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Antimony vs bismuth: structural differences in Cat{[MCl5](I2)} halogen bond-linked supramolecular complexes

Four new hybrid chloroantimonates(III) and chrorobismuthates(III) with halogen bond-linked I2, (H2bpe){[MCl5](I2)} (M = Sb(III) (1); M = Bi(III) (2); bpe – 1,2-bis(4-pyridil)ethane) and (H2bpp){[MCl5](I2)} – (M = Sb(III) (3); M = Bi(III) (4); bpp = 1,3-bis(4-pyridil)propane)) were synthesized via reaction between Sb2O3/Bi2O3, I2 and corresponding bis(pyridines) in HCl. Despite sharing the same formulae of supramolecular anionic parts, they show significant structural diversity, revealing three different structural types. Features of halogen bond in 1-4 were examined by theoretical methods.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.