Jinjin Zhang, Mingjie Tang, Siyuan Yang, Hongqing Li, Guangbin Cheng, Yongxing Tang, Ming Liu
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引用次数: 0
摘要
Ming Liu等人在其研究文章（e202501187）中报道，设计了一种分子笼，通过集体弱相互作用来捕获环- n5 - h（一种高度不稳定的阴离子）。通过刻意避免强相互作用，笼形结构有效地保留了环- n5 -c的芳香性，同时通过单晶x射线衍射直接监测其分解。
Outside Front Cover: Direct Observation of Cyclo-Pentazolate Anion Decomposition in a Tailored Molecular Trap (Angew. Chem. 22/2025)
A molecular cage was designed to trap cyclo-N5ˉ, a highly unstable anion, through collective weak interactions, as reported by Ming Liu et al. in their Research Article (e202501187). By intentionally avoiding strong interactions, the cage effectively preserved the aromaticity of cyclo-N5ˉ, while its decomposition was directly monitored via single-crystal X-ray diffraction.
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