João Paulo Vita Damasceno, Valerio Francesco Annese*, Giulia Coco, Lauro Tatsuo Kubota and Mario Caironi*,
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Inkjet Printable Conductive Activated Carbon Ink from Sustainable Sources
Inkjet printing offers an attractive manufacturing method for flexible and large-area electronics, yet formulating sustainable inks not derived from fossil fuels represents a major challenge toward environmentally friendly technologies. Here, we present a conductive ink formulated for inkjet printing, consisting only of renewable and nontoxic components, namely electrically conductive activated carbon nanoparticles, ethyl cellulose as binder and stabilizer, and ethanol-terpineol mixture as the dispersant. The ink is composed of activated carbon nanoparticles with a diameter between 30 and 120 nm and exhibits high colloidal stability, dynamic viscosity and surface tension within an ideal range for inkjet printing. The ink produces electrically conductive patterns, achieving a resistivity of 6.6 Ω cm. Such result enables the manufacturing of printed resistive elements in electronic circuits, where the sheet resistance is tunable by the drop spacing and/or layers number of the printing process. As a proof-of-concept of future printed sustainable sensors, we employed this formulation to produce a resistive humidity sensor capable of detecting the moisture content in the air exhaled during respiration. The conductive ink herein presented is a step toward the quest for sustainable materials for environmentally friendly printed electronics.
期刊介绍:
ACS Applied Electronic Materials is an interdisciplinary journal publishing original research covering all aspects of electronic materials. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials science, engineering, optics, physics, and chemistry into important applications of electronic materials. Sample research topics that span the journal's scope are inorganic, organic, ionic and polymeric materials with properties that include conducting, semiconducting, superconducting, insulating, dielectric, magnetic, optoelectronic, piezoelectric, ferroelectric and thermoelectric.
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