金属包覆{M2(H2O)[P4Mo6O31]2}基磷钼酸盐（M = Al3+, Ga3+）。

IF 4.7 2区化学 Q1 CHEMISTRY, INORGANIC & NUCLEAR

Inorganic Chemistry Pub Date : 2025-05-25 DOI:10.1021/acs.inorgchem.5c01379

Yu-Qing Liu,Hao-Xue Bi,Zi-Yi Zhang,Yuan-Yuan Ma,Ya-Qi Zhang,Jing Du,Zheng-Guo Lin,Zhan-Gang Han

引用次数: 0

摘要

通过调整还原剂，合成了IIIA族金属Al3+/Ga3+包封{M2(H2O)[P4Mo6O31]2}基的磷钼酸盐，其中两个[P4MoVI4MoV2O31]8-半单元以正面方式连接，两侧由两个M3+/[M(H2O)]3+阳离子包封。这类{M2(H2O)[P4Mo6O31]2}杂化物在Cr（VI）还原反应中表现出优异的光催化活性。

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Group IIIA Metal-Capped {M2(H2O)[P4Mo6O31]2}-Based Phosphomolybdates (M = Al3+, Ga3+).

Group IIIA metal Al3+/Ga3+-capped {M2(H2O)[P4Mo6O31]2}-based phosphomolybdates were synthesized by adjusting the reducing agents, in which two [P4MoVI4MoV2O31]8- half-units are joined in a face-to-face mode and are capped by two M3+/[M(H2O)]3+ cations on both sides. This type of {M2(H2O)[P4Mo6O31]2} hybrids showed excellent photocatalytic activities in the Cr(VI) reduction reaction.

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来源期刊

Inorganic Chemistry 化学-无机化学与核化学

CiteScore

7.60

自引率

13.00%

发文量

1960

审稿时长

1.9 months

期刊介绍： Inorganic Chemistry publishes fundamental studies in all phases of inorganic chemistry. Coverage includes experimental and theoretical reports on quantitative studies of structure and thermodynamics, kinetics, mechanisms of inorganic reactions, bioinorganic chemistry, and relevant aspects of organometallic chemistry, solid-state phenomena, and chemical bonding theory. Emphasis is placed on the synthesis, structure, thermodynamics, reactivity, spectroscopy, and bonding properties of significant new and known compounds.