通过自动固定大气CO2，将4f和3d-4f簇组装成单分子磁铁

IF 3.5 3区化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR

Dalton Transactions Pub Date : 2025-05-26 DOI:10.1039/d5dt01070e

Cai-Ming Liu

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引用次数: 0

摘要

通过将二氧化碳固定在空气中进行簇组装的新方法为开发新型单分子磁体（SMMs）提供了一种创新方法。4f簇smm和3d-4f簇smm都可以通过这种绿色途径组装。即使在引入手性和/或分子间氢键之后，这种smm也可以在纳米尺度上进一步制成多功能分子材料。本文简要介绍了利用空气中CO2固定组装的4f簇smm和3d-4f簇smm，并展望了该领域的发展前景。

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Assembling 4f and 3d-4f clusters as single-molecule magnets by automatic fixation of atmospheric CO2

Emerging methods for cluster assembly through the fixation of CO₂ in air provide an innovative approach to the development of novel single-molecule magnets (SMMs). Both 4f cluster SMMs and 3d-4f cluster SMMs may be assembled using this green pathway. Even after the introduction of chirality and/or intermolecular hydrogen bonds, such SMMs can be further made into multifunctional molecular materials at the nanoscale. In this paper, we briefly review 4f cluster SMMs and 3d-4f cluster SMMs assembled by the fixation of CO₂ in air, and outlook the promising future prospects in this field.

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来源期刊

Dalton Transactions 化学-无机化学与核化学

CiteScore

6.60

自引率

7.50%

发文量

1832

审稿时长

1.5 months

期刊介绍： Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.