{"title":"环金属化磷基铱(III)光催化剂","authors":"Oussama Fayafrou , Juliette Zanzi , Carine Duhayon , Jean-Baptiste Sortais , Olivier Baslé , Yves Canac","doi":"10.1039/d5cc02320c","DOIUrl":null,"url":null,"abstract":"<div><div>A novel class of cyclometallated photoactive iridium(<span>iii</span>) complexes containing phosphonium ylide ligands has been synthesized and thoroughly characterized. Their photophysical and redox properties have been systematically investigated and employed in photocatalytic applications. Notably, these complexes exhibit high activity in visible-light-mediated EnT and SET processes.</div></div>","PeriodicalId":67,"journal":{"name":"Chemical Communications","volume":"61 54","pages":"Pages 9932-9935"},"PeriodicalIF":4.2000,"publicationDate":"2025-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Cyclometallated phosphonium ylide-based iridium(iii) photocatalysts†\",\"authors\":\"Oussama Fayafrou , Juliette Zanzi , Carine Duhayon , Jean-Baptiste Sortais , Olivier Baslé , Yves Canac\",\"doi\":\"10.1039/d5cc02320c\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><div>A novel class of cyclometallated photoactive iridium(<span>iii</span>) complexes containing phosphonium ylide ligands has been synthesized and thoroughly characterized. Their photophysical and redox properties have been systematically investigated and employed in photocatalytic applications. Notably, these complexes exhibit high activity in visible-light-mediated EnT and SET processes.</div></div>\",\"PeriodicalId\":67,\"journal\":{\"name\":\"Chemical Communications\",\"volume\":\"61 54\",\"pages\":\"Pages 9932-9935\"},\"PeriodicalIF\":4.2000,\"publicationDate\":\"2025-05-30\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Chemical Communications\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://www.sciencedirect.com/org/science/article/pii/S1359734525011838\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1359734525011838","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
A novel class of cyclometallated photoactive iridium(iii) complexes containing phosphonium ylide ligands has been synthesized and thoroughly characterized. Their photophysical and redox properties have been systematically investigated and employed in photocatalytic applications. Notably, these complexes exhibit high activity in visible-light-mediated EnT and SET processes.
期刊介绍:
ChemComm (Chemical Communications) is renowned as the fastest publisher of articles providing information on new avenues of research, drawn from all the world''s major areas of chemical research.