磁场在废水萃取处理中的应用

IF 0.5 4区 化学 Q4 CHEMISTRY, ANALYTICAL
A. A. Gasanov, E. A. Guseinova
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引用次数: 0

摘要

工业企业面临的主要挑战之一涉及处理过的水的再利用。在油漆和涂料生产中,水会被各种有机溶剂污染,包括丁二醇、乙酸、乙酰丙酮等。对这些水进行有效处理并将其重新纳入技术过程是关键目标。本研究报道了在磁感应强度为20 mT的磁场作用下,单级液相废水处理的结果,丁二醇的净化效率为99.3%,乙酸的净化效率为99.1%,乙酰丙酮的净化效率为99.8%。以异丙醇为萃取剂。废水和萃取剂的体积流量分别为3.0和0.3 dm3/h。萃取器直径为dextr = 0.03 m,萃取剂通过的开口为dop = 0.5 mm。利用差分细胞模型,计算了平衡相中各组分沿装置高度的浓度,以及理论级数和萃取器高度。在第20个细胞中,萃液中各成分的浓度几乎与初始浓度相同,从而假设有20个理论阶段。假设理论级之间的距离为Δh = 0.05 m,则计算出直径为0.03 m的萃取器高度为:Hextr = 20 × 0.05 = 1.0 m。并计算了沿提取器高度方向的成分提取度。提出了在磁场作用下单级液-液萃取处理有机溶剂污染废水达到最大允许浓度(MPCs)的零废工艺。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Application of a Magnetic Field in Liquid Extraction Treatment of Wastewater

One of the primary challenges faced by industrial enterprises involves the reuse of treated water. In paint and coating production, water becomes contaminated with various organic solvents, including butyl glycol, acetic acid, acetylacetone, and others. Efficient treatment and reintegration of this water into the technological process represent critical objectives. This study reports the results of single-stage liquid-phase wastewater treatment under the influence of a magnetic field with a magnetic induction of 20 mT, achieving purification efficiencies of 99.3% for butyl glycol, 99.1% for acetic acid, and 99.8% for acetylacetone. Isopropyl alcohol served as the extractant. The volumetric flow rates of wastewater and extractant were 3.0 and 0.3 dm3/h, respectively. The diameter of the extractor and the openings through which the extractant passes were dextr = 0.03 m and dop = 0.5 mm, respectively. Using a differential cell model, the concentrations of components in equilibrium phases along the height of the apparatus were calculated, along with the number of theoretical stages and the extractor height. The concentrations of components in the raffinate at the 20th cell were nearly identical to their initial concentrations, leading to the assumption of 20 theoretical stages. Given that the distance between theoretical stages is Δh = 0.05 m, the height of the extractor, with a diameter of 0.03 m, was calculated to be Hextr = 20 × 0.05 = 1.0 m. The degree of component extraction along the height of the extractor was also calculated. A zero-waste technology was proposed for treating wastewater contaminated with organic solvents to achieve maximum permissible concentrations (MPCs) using single-stage liquid–liquid extraction under the action of a magnetic field.

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来源期刊
Journal of Water Chemistry and Technology
Journal of Water Chemistry and Technology CHEMISTRY, APPLIED-CHEMISTRY, ANALYTICAL
自引率
0.00%
发文量
51
审稿时长
>12 weeks
期刊介绍: Journal of Water Chemistry and Technology focuses on water and wastewater treatment, water pollution monitoring, water purification, and similar topics. The journal publishes original scientific theoretical and experimental articles in the following sections: new developments in the science of water; theoretical principles of water treatment and technology; physical chemistry of water treatment processes; analytical water chemistry; analysis of natural and waste waters; water treatment technology and demineralization of water; biological methods of water treatment; and also solicited critical reviews summarizing the latest findings. The journal welcomes manuscripts from all countries in the English or Ukrainian language. All manuscripts are peer-reviewed.
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