在煤油中合成纳米金刚石

IF 0.6 4区 物理与天体物理 Q4 MECHANICS
B. A. Timerkaev, A. S. Vladimirov, B. R. Shakirov, G. R. Farkhutdinova, R. R. Shaykhattarov, I. G. Galeev
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引用次数: 0

摘要

本文考虑了在煤油中石墨电极之间组织电弧放电的可能性,并在放电区域提供氩气,应用于碳纳米结构的合成。氩气的存在取决于在低粘度液体介质中保持低电流放电的条件。结果表明,在煤油中氩-烃弧放电可以作为合成纳米金刚石的有效手段。合成的纳米结构看起来像一条形状和大小大致相同的数字链。此外,这些链在任何地方都不会被打断,从而构成了一种纳米金刚石晶体。这可能是由于一个粒子进入液体,从另一端开始形成一个新的粒子。合成的纳米金刚石的尺寸从40纳米到100纳米不等,并一个接一个地形成线性排列。这些结果中最有趣的是,除了纳米金刚石外,在其附近没有其他纳米结构,这可能是由于氢的存在,氢与未结合的碳原子发生反应,并将它们从放电区域移除。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of Nanodiamonds in Kerosene

This article considers the possibilities of organizing an arc discharge between graphite electrodes in kerosene with argon supply to the discharge area as applied to the synthesis of carbon nanostructures. The presence of argon was dictated by the conditions of maintaining a low-current discharge in a liquid medium with low viscosity. It is shown that an argon–hydrocarbon arc discharge in kerosene can serve as an effective tool for synthesizing nanodiamonds. The synthesized nanostructures look like a chain of figures that are approximately identical in shape and size. Moreover, these chains are not interrupted anywhere, making up a kind of crystal of nanodiamonds. This may be due to the entry of a particle into a liquid, from the other end of which a new particle begins to form. The synthesized nanodiamonds have sizes from 40 to 100 nm and are built into a linear row one after another. The most interesting thing about these results is that in the immediate vicinity there are no other nanostructures except nanodiamonds, which may be due to the presence of hydrogen, which reacts with unbound carbon atoms and removes them from the discharge area.

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来源期刊
Doklady Physics
Doklady Physics 物理-力学
CiteScore
1.40
自引率
12.50%
发文量
12
审稿时长
4-8 weeks
期刊介绍: Doklady Physics is a journal that publishes new research in physics of great significance. Initially the journal was a forum of the Russian Academy of Science and published only best contributions from Russia in the form of short articles. Now the journal welcomes submissions from any country in the English or Russian language. Every manuscript must be recommended by Russian or foreign members of the Russian Academy of Sciences.
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