连续制造强大的,可扩展的,高产的,和可持续的材料从杨木

IF 7.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY
Abdolrahim A. Rafi, Staffan K. Nyström, Narbe Shamirza, Pietro Bartocci, Tatjana Karpenja, Cherryleen Garcia-Lindgren, Per Engstrand* and Armando Córdova*, 
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引用次数: 0

摘要

具有高强度的轻质材料在交通运输、运动器材、建筑、汽车和航空航天等领域的先进应用是理想的。白杨生长迅速,可燃性低,可再生,易得。在这项研究中,我们提出了一种连续、高产、高效、可扩展和可持续的方法,通过协同选择性化学改性和连续热压,从杨木中制备强材料。FTIR分析揭示了木材聚合物化学成分的变化,包括阴离子基团的引入,而SEM图像显示了形态和结构的变化,如光滑的表面和更紧凑的木材结构。该策略通过结合增强的离子键和氢键与纤维素纳米原纤维的排列以及通过交联反应软化解聚木质素的固化,实现了高达258 MPa(530%)的抗拉强度提高。这项工作展示了在节能和温和改性条件下连续大规模生产轻质,坚固的结构材料,适用于下一代先进木材材料的绿色制造。一种连续的、可扩展的、高产的、可持续的方法,通过选择性的化学改性和热压,从白杨中创造出坚固、轻质的材料。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Continuous Fabrication of Strong, Scalable, High-Yield, and Sustainable Materials from Aspen

Lightweight materials with high strength are desirable for advanced applications in transportation, sports equipment, construction, automotive, and aerospace. Aspen is fast growing, has low flammability, and is renewable and readily available. In this study, we present a continuous, high-yielding, efficient, scalable, and sustainable approach for the fabrication of strong materials from aspen by synergistic selective chemical modification and continuous hot pressing. FTIR analysis revealed changes in the chemical composition of the wood polymers, including the introduction of anionic groups, while SEM images showed morphological and structural transformations such as smoother surfaces and a more compact wood structure. The proposed strategy achieved up to 258 MPa (530% increase) in tensile strength by combining enhanced ion-bonding and hydrogen-bonding with the alignment of cellulose nanofibrils and the solidification of softened, depolymerized lignin through cross-linking reactions. This work demonstrates the continuous large-scale production of lightweight, strong structural materials under energy-efficient and mild modification conditions, suitable for the green fabrication of next-generation advanced materials from wood.

A continuous, scalable, high-yielding, and sustainable method creates strong, lightweight materials from aspen via selective chemical modification and hot pressing.

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来源期刊
ACS Sustainable Chemistry & Engineering
ACS Sustainable Chemistry & Engineering CHEMISTRY, MULTIDISCIPLINARY-ENGINEERING, CHEMICAL
CiteScore
13.80
自引率
4.80%
发文量
1470
审稿时长
1.7 months
期刊介绍: ACS Sustainable Chemistry & Engineering is a prestigious weekly peer-reviewed scientific journal published by the American Chemical Society. Dedicated to advancing the principles of green chemistry and green engineering, it covers a wide array of research topics including green chemistry, green engineering, biomass, alternative energy, and life cycle assessment. The journal welcomes submissions in various formats, including Letters, Articles, Features, and Perspectives (Reviews), that address the challenges of sustainability in the chemical enterprise and contribute to the advancement of sustainable practices. Join us in shaping the future of sustainable chemistry and engineering.
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