{"title":"氢转移在功能分子材料和器件中的作用","authors":"Enyu Zhang, Liping Bai, Zhiping Chen, Aobo Zhang, Yingbo Tang, Jushang Ran, Shuai Wang, Jinying Wang*, Chuancheng Jia* and Xuefeng Guo*, ","doi":"10.1021/prechem.4c0009710.1021/prechem.4c00097","DOIUrl":null,"url":null,"abstract":"<p >Hydrogen transfer is a fundamental chemical process critical to the design and application of organic molecules and functional devices. By uncovering the dynamic interactions between atoms within molecules, hydrogen transfer research offers innovative pathways for creating advanced functional materials and devices. These advancements have driven progress in areas such as optoelectronics, molecular switches, and bioimaging. This review explores the various forms of hydrogen transfer, including hydrogen atom, proton, and hydride transfer, highlighting their mechanisms and key reactions. It also examines the integration of these processes into molecular devices, including single-molecule systems, molecular films, and organic frameworks. Future directions emphasize precise control of hydrogen transfer pathways, development of highly selective and efficient reaction systems, and the design of robust devices based on these processes. These efforts aim to enhance device performance and broaden applications in intelligent materials, integrated functions, and information technology.</p>","PeriodicalId":29793,"journal":{"name":"Precision Chemistry","volume":"3 5","pages":"233–260 233–260"},"PeriodicalIF":6.2000,"publicationDate":"2025-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/prechem.4c00097","citationCount":"0","resultStr":"{\"title\":\"Role of Hydrogen Transfer in Functional Molecular Materials and Devices\",\"authors\":\"Enyu Zhang, Liping Bai, Zhiping Chen, Aobo Zhang, Yingbo Tang, Jushang Ran, Shuai Wang, Jinying Wang*, Chuancheng Jia* and Xuefeng Guo*, \",\"doi\":\"10.1021/prechem.4c0009710.1021/prechem.4c00097\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p >Hydrogen transfer is a fundamental chemical process critical to the design and application of organic molecules and functional devices. By uncovering the dynamic interactions between atoms within molecules, hydrogen transfer research offers innovative pathways for creating advanced functional materials and devices. These advancements have driven progress in areas such as optoelectronics, molecular switches, and bioimaging. This review explores the various forms of hydrogen transfer, including hydrogen atom, proton, and hydride transfer, highlighting their mechanisms and key reactions. It also examines the integration of these processes into molecular devices, including single-molecule systems, molecular films, and organic frameworks. Future directions emphasize precise control of hydrogen transfer pathways, development of highly selective and efficient reaction systems, and the design of robust devices based on these processes. These efforts aim to enhance device performance and broaden applications in intelligent materials, integrated functions, and information technology.</p>\",\"PeriodicalId\":29793,\"journal\":{\"name\":\"Precision Chemistry\",\"volume\":\"3 5\",\"pages\":\"233–260 233–260\"},\"PeriodicalIF\":6.2000,\"publicationDate\":\"2025-03-11\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://pubs.acs.org/doi/epdf/10.1021/prechem.4c00097\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Precision Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://pubs.acs.org/doi/10.1021/prechem.4c00097\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Precision Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://pubs.acs.org/doi/10.1021/prechem.4c00097","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Role of Hydrogen Transfer in Functional Molecular Materials and Devices
Hydrogen transfer is a fundamental chemical process critical to the design and application of organic molecules and functional devices. By uncovering the dynamic interactions between atoms within molecules, hydrogen transfer research offers innovative pathways for creating advanced functional materials and devices. These advancements have driven progress in areas such as optoelectronics, molecular switches, and bioimaging. This review explores the various forms of hydrogen transfer, including hydrogen atom, proton, and hydride transfer, highlighting their mechanisms and key reactions. It also examines the integration of these processes into molecular devices, including single-molecule systems, molecular films, and organic frameworks. Future directions emphasize precise control of hydrogen transfer pathways, development of highly selective and efficient reaction systems, and the design of robust devices based on these processes. These efforts aim to enhance device performance and broaden applications in intelligent materials, integrated functions, and information technology.
期刊介绍:
Chemical research focused on precision enables more controllable predictable and accurate outcomes which in turn drive innovation in measurement science sustainable materials information materials personalized medicines energy environmental science and countless other fields requiring chemical insights.Precision Chemistry provides a unique and highly focused publishing venue for fundamental applied and interdisciplinary research aiming to achieve precision calculation design synthesis manipulation measurement and manufacturing. It is committed to bringing together researchers from across the chemical sciences and the related scientific areas to showcase original research and critical reviews of exceptional quality significance and interest to the broad chemistry and scientific community.